{"id":6211,"date":"2025-02-14T17:54:04","date_gmt":"2025-02-14T09:54:04","guid":{"rendered":"https:\/\/www.xindianchem.com\/6211.html"},"modified":"2025-02-14T17:54:04","modified_gmt":"2025-02-14T09:54:04","slug":"%e7%83%ad%e6%95%8f%e5%bb%b6%e8%bf%9f%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e4%b8%8d%e5%90%8c%e6%b0%94%e5%80%99%e6%9d%a1%e4%bb%b6%e4%b8%8b%e6%80%a7%e8%83%bd%e8%a1%a8%e7%8e%b0%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"https:\/\/www.xindianchem.com\/6211.html","title":{"rendered":"\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u6027\u80fd\u8868\u73b0\u7684\u7814\u7a76\u62a5\u544a"},"content":{"rendered":"<h3>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u7684\u6982\u8ff0<\/h3>\n<p>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08Thermosensitive Delayed Catalyst, TDC\uff09\u662f\u4e00\u7c7b\u80fd\u591f\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u89e6\u53d1\u5316\u5b66\u53cd\u5e94\u6216\u6539\u53d8\u53cd\u5e94\u901f\u7387\u7684\u50ac\u5316\u5242\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5316\u5de5\u3001\u5236\u836f\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\uff0c\u5c24\u5176\u662f\u5728\u9700\u8981\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u65f6\u95f4\u6216\u6e29\u5ea6\u6761\u4ef6\u7684\u60c5\u51b5\u4e0b\u3002\u4e0e\u4f20\u7edf\u7684\u50ac\u5316\u5242\u76f8\u6bd4\uff0cTDC\u7684\u5927\u7279\u70b9\u662f\u5176\u6d3b\u6027\u53d7\u5230\u6e29\u5ea6\u7684\u663e\u8457\u5f71\u54cd\uff0c\u80fd\u591f\u5728\u8bbe\u5b9a\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u5ef6\u8fdf\u50ac\u5316\u4f5c\u7528\u7684\u542f\u52a8\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u53cd\u5e94\u8fdb\u7a0b\u7684\u7cbe\u51c6\u8c03\u63a7\u3002<\/p>\n<p>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u7684\u5de5\u4f5c\u539f\u7406\u57fa\u4e8e\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u548c\u70ed\u54cd\u5e94\u7279\u6027\u3002\u901a\u5e38\uff0cTDC\u7531\u4e00\u4e2a\u6838\u5fc3\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u548c\u4e00\u4e2a\u6e29\u5ea6\u654f\u611f\u7684\u4fdd\u62a4\u57fa\u56e2\u7ec4\u6210\u3002\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u4fdd\u62a4\u57fa\u56e2\u80fd\u591f\u6709\u6548\u5730\u6291\u5236\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u66b4\u9732\uff0c\u963b\u6b62\u53cd\u5e94\u7684\u53d1\u751f\u3002\u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u4fdd\u62a4\u57fa\u56e2\u9010\u6e10\u89e3\u79bb\u6216\u53d1\u751f\u7ed3\u6784\u53d8\u5316\uff0c\u66b4\u9732\u51fa\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\uff0c\u4ece\u800c\u542f\u52a8\u50ac\u5316\u53cd\u5e94\u3002\u8fd9\u79cd\u6e29\u5ea6\u4f9d\u8d56\u6027\u7684\u6fc0\u6d3b\u673a\u5236\u4f7f\u5f97TDC\u5728\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u5bf9\u50ac\u5316\u53cd\u5e94\u63a7\u5236\u9700\u6c42\u7684\u589e\u52a0\uff0cTDC\u7684\u7814\u7a76\u548c\u5e94\u7528\u5f97\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u56fd\u5916\u6587\u732e\u4e2d\uff0c\u5982\u300aJournal of Catalysis\u300b\u548c\u300aChemical Reviews\u300b\u7b49\u6743\u5a01\u671f\u520a\uff0c\u591a\u6b21\u62a5\u9053\u4e86\u5173\u4e8eTTC\u7684\u65b0\u7814\u7a76\u6210\u679c\u3002\u56fd\u5185\u8457\u540d\u6587\u732e\u5982\u300a\u50ac\u5316\u5b66\u62a5\u300b\u548c\u300a\u5316\u5b66\u5b66\u62a5\u300b\u4e5f\u53d1\u8868\u4e86\u5927\u91cf\u5173\u4e8eTDC\u7684\u5b9e\u9a8c\u6570\u636e\u548c\u7406\u8bba\u5206\u6790\u3002\u8fd9\u4e9b\u7814\u7a76\u4e0d\u4ec5\u63ed\u793a\u4e86TDC\u7684\u5fae\u89c2\u673a\u5236\uff0c\u8fd8\u4e3a\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u53c2\u8003\u4f9d\u636e\u3002<\/p>\n<p>\u672c\u6587\u5c06\u91cd\u70b9\u63a2\u8ba8\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u901a\u8fc7\u7cfb\u7edf\u5206\u6790\u5176\u5728\u9ad8\u6e29\u3001\u4f4e\u6e29\u3001\u9ad8\u6e7f\u5ea6\u3001\u4f4e\u6e7f\u5ea6\u7b49\u73af\u5883\u4e2d\u7684\u884c\u4e3a\uff0c\u63ed\u793a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u4f18\u52bf\u548c\u6311\u6218\u3002\u6587\u7ae0\u5c06\u4ece\u4ea7\u54c1\u53c2\u6570\u3001\u5b9e\u9a8c\u8bbe\u8ba1\u3001\u6570\u636e\u5206\u6790\u7b49\u591a\u4e2a\u89d2\u5ea6\u8fdb\u884c\u6df1\u5165\u8ba8\u8bba\uff0c\u5e76\u5f15\u7528\u56fd\u5185\u5916\u76f8\u5173\u6587\u732e\uff0c\u529b\u6c42\u4e3a\u8bfb\u8005\u63d0\u4f9b\u5168\u9762\u3001\u8be6\u5c3d\u7684\u7814\u7a76\u62a5\u544a\u3002<\/p>\n<h3>\u4ea7\u54c1\u53c2\u6570\u4e0e\u5206\u7c7b<\/h3>\n<p>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TDC\uff09\u6839\u636e\u5176\u5316\u5b66\u7ec4\u6210\u3001\u7ed3\u6784\u7279\u5f81\u4ee5\u53ca\u5e94\u7528\u9886\u57df\u7684\u4e0d\u540c\uff0c\u53ef\u4ee5\u5206\u4e3a\u591a\u4e2a\u7c7b\u522b\u3002\u6bcf\u79cd\u7c7b\u578b\u7684TDC\u90fd\u5177\u6709\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u9002\u7528\u4e8e\u4e0d\u540c\u7684\u53cd\u5e94\u4f53\u7cfb\u548c\u5de5\u4f5c\u73af\u5883\u3002\u4ee5\u4e0b\u662f\u51e0\u79cd\u5e38\u89c1\u7684TDC\u7c7b\u578b\u53ca\u5176\u4e3b\u8981\u53c2\u6570\uff1a<\/p>\n<h4>1. \u6709\u673a\u91d1\u5c5e\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p><strong>\u7279\u70b9<\/strong>\uff1a\u6709\u673a\u91d1\u5c5eTDC\u662f\u901a\u8fc7\u6709\u673a\u914d\u4f53\u4e0e\u91d1\u5c5e\u79bb\u5b50\u7ed3\u5408\u5f62\u6210\u7684\u590d\u5408\u7269\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u9009\u62e9\u6027\u3002\u5e38\u89c1\u7684\u91d1\u5c5e\u79bb\u5b50\u5305\u62ec\u94af\uff08Pd\uff09\u3001\u94c2\uff08Pt\uff09\u3001\u948c\uff08Ru\uff09\u7b49\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e2d\u5fc3\u901a\u5e38\u88ab\u6709\u673a\u914d\u4f53\u5305\u88f9\uff0c\u5728\u4f4e\u6e29\u4e0b\u4fdd\u6301\u60f0\u6027\uff0c\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\uff0c\u914d\u4f53\u89e3\u79bb\uff0c\u66b4\u9732\u51fa\u6d3b\u6027\u4e2d\u5fc3\u3002<\/p>\n<p><strong>\u5178\u578b\u4ea7\u54c1<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>Pd(II)\u914d\u5408\u7269<\/strong>\uff1a\u5982PdCl\u2082(PPh\u2083)\u2082\uff0c\u5e38\u7528\u4e8e\u70ef\u70c3\u52a0\u6c22\u53cd\u5e94\u3002<\/li>\n<li><strong>Ru(III)\u914d\u5408\u7269<\/strong>\uff1a\u5982RuCl\u2083\u00b7xH\u2082O\uff0c\u9002\u7528\u4e8e\u7fb0\u57fa\u5316\u5408\u7269\u7684\u8fd8\u539f\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong>\uff1a<\/th>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u5178\u578b\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6d3b\u5316\u6e29\u5ea6<\/td>\n<td>\u00b0C<\/td>\n<td>60-120<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6548\u7387<\/td>\n<td>mol\/mol<\/td>\n<td>10\u207b\u2076 &#8211; 10\u207b\u2075<\/td>\n<\/tr>\n<tr>\n<td>\u7a33\u5b9a\u6027<\/td>\n<td>\u5c0f\u65f6<\/td>\n<td>&gt; 100 (\u5ba4\u6e29)<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6eb6\u5242<\/td>\n<td>\u3001\u7532<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>2. \u9176\u7c7b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p><strong>\u7279\u70b9<\/strong>\uff1a\u9176\u7c7bTDC\u662f\u4e00\u79cd\u751f\u7269\u50ac\u5316\u5242\uff0c\u5177\u6709\u9ad8\u5ea6\u7279\u5f02\u6027\u548c\u9ad8\u6548\u6027\u3002\u5b83\u4eec\u7684\u6d3b\u6027\u4e2d\u5fc3\u901a\u5e38\u7531\u86cb\u767d\u8d28\u7ed3\u6784\u4e2d\u7684\u6c28\u57fa\u9178\u6b8b\u57fa\u7ec4\u6210\uff0c\u80fd\u591f\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u53d1\u6325\u50ac\u5316\u4f5c\u7528\u3002\u9176\u7c7bTDC\u7684\u4f18\u52bf\u5728\u4e8e\u5176\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u548c\u73af\u5883\u53cb\u597d\u6027\uff0c\u4f46\u5176\u70ed\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u5bb9\u6613\u5931\u6d3b\u3002<\/p>\n<p><strong>\u5178\u578b\u4ea7\u54c1<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u8102\u80aa\u9176<\/strong>\uff1a\u5982Novozym 435\uff0c\u9002\u7528\u4e8e\u916f\u4ea4\u6362\u53cd\u5e94\u3002<\/li>\n<li><strong>\u8fc7\u6c27\u5316\u6c22\u9176<\/strong>\uff1a\u5982Catalase\uff0c\u7528\u4e8e\u5206\u89e3\u8fc7\u6c27\u5316\u6c22\u3002<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong>\uff1a<\/th>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u5178\u578b\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6d3b\u5316\u6e29\u5ea6<\/td>\n<td>\u00b0C<\/td>\n<td>30-50<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6548\u7387<\/td>\n<td>U\/mg<\/td>\n<td>100-500<\/td>\n<\/tr>\n<tr>\n<td>\u7a33\u5b9a\u6027<\/td>\n<td>\u5c0f\u65f6<\/td>\n<td>10-20 (\u5ba4\u6e29)<\/td>\n<\/tr>\n<tr>\n<td>\u9002pH<\/td>\n<td>&#8211;<\/td>\n<td>7.0-8.5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>3. \u7eb3\u7c73\u9897\u7c92\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p><strong>\u7279\u70b9<\/strong>\uff1a\u7eb3\u7c73\u9897\u7c92TDC\u662f\u7531\u91d1\u5c5e\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u7c92\u5b50\u7ec4\u6210\u7684\u50ac\u5316\u5242\uff0c\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u53ef\u4ee5\u901a\u8fc7\u4fee\u9970\u4e0d\u540c\u7684\u5b98\u80fd\u56e2\u6765\u8c03\u8282\u5176\u70ed\u54cd\u5e94\u7279\u6027\uff0c\u4f7f\u5176\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u8868\u73b0\u51fa\u5ef6\u8fdf\u50ac\u5316\u6548\u5e94\u3002<\/p>\n<p><strong>\u5178\u578b\u4ea7\u54c1<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u91d1\u7eb3\u7c73\u9897\u7c92\uff08Au NPs\uff09<\/strong>\uff1a\u9002\u7528\u4e8e\u5149\u50ac\u5316\u548c\u7535\u50ac\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>\u4e8c\u6c27\u5316\u949b\u7eb3\u7c73\u9897\u7c92\uff08TiO\u2082 NPs\uff09<\/strong>\uff1a\u5e38\u7528\u4e8e\u5149\u89e3\u6c34\u5236\u6c22\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong>\uff1a<\/th>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u5178\u578b\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6d3b\u5316\u6e29\u5ea6<\/td>\n<td>\u00b0C<\/td>\n<td>80-150<\/td>\n<\/tr>\n<tr>\n<td>\u7c92\u5f84<\/td>\n<td>nm<\/td>\n<td>5-50<\/td>\n<\/tr>\n<tr>\n<td>\u6bd4\u8868\u9762\u79ef<\/td>\n<td>m\u00b2\/g<\/td>\n<td>50-200<\/td>\n<\/tr>\n<tr>\n<td>\u7a33\u5b9a\u6027<\/td>\n<td>\u5c0f\u65f6<\/td>\n<td>&gt; 200 (\u5ba4\u6e29)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>4. \u805a\u5408\u7269\u57fa\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p><strong>\u7279\u70b9<\/strong>\uff1a\u805a\u5408\u7269\u57faTDC\u662f\u7531\u529f\u80fd\u6027\u805a\u5408\u7269\u4e0e\u50ac\u5316\u5242\u590d\u5408\u800c\u6210\u7684\u6750\u6599\uff0c\u5177\u6709\u826f\u597d\u7684\u673a\u68b0\u6027\u80fd\u548c\u70ed\u54cd\u5e94\u6027\u3002\u805a\u5408\u7269\u57fa\u8d28\u53ef\u4ee5\u901a\u8fc7\u4ea4\u8054\u6216\u5171\u805a\u7684\u65b9\u5f0f\u5f15\u5165\u6e29\u5ea6\u654f\u611f\u7684\u5355\u4f53\uff0c\u5982N-\u5f02\u4e19\u57fa\u4e19\u70ef\u9170\u80fa\uff08NIPAM\uff09\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u6e29\u5ea6\u8c03\u63a7\u3002<\/p>\n<p><strong>\u5178\u578b\u4ea7\u54c1<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u805aNIPAM\/Pd\u590d\u5408\u6750\u6599<\/strong>\uff1a\u9002\u7528\u4e8e\u6709\u673a\u5408\u6210\u53cd\u5e94\u3002<\/li>\n<li><strong>\u805a\u4e19\u70ef\u9178\/Fe\u2083O\u2084\u590d\u5408\u6750\u6599<\/strong>\uff1a\u7528\u4e8e\u78c1\u6027\u50ac\u5316\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong>\uff1a<\/th>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u5178\u578b\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6d3b\u5316\u6e29\u5ea6<\/td>\n<td>\u00b0C<\/td>\n<td>35-60<\/td>\n<\/tr>\n<tr>\n<td>\u805a\u5408\u5ea6<\/td>\n<td>&#8211;<\/td>\n<td>100-500<\/td>\n<\/tr>\n<tr>\n<td>\u7a33\u5b9a\u6027<\/td>\n<td>\u5c0f\u65f6<\/td>\n<td>&gt; 50 (\u5ba4\u6e29)<\/td>\n<\/tr>\n<tr>\n<td>\u542b\u6c34\u91cf<\/td>\n<td>%<\/td>\n<td>5-15<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>5. \u667a\u80fd\u54cd\u5e94\u578b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p><strong>\u7279\u70b9<\/strong>\uff1a\u667a\u80fd\u54cd\u5e94\u578bTDC\u662f\u4e00\u79cd\u96c6\u6210\u4e86\u591a\u79cd\u523a\u6fc0\u54cd\u5e94\u529f\u80fd\u7684\u50ac\u5316\u5242\uff0c\u9664\u4e86\u6e29\u5ea6\u5916\uff0c\u8fd8\u53ef\u4ee5\u5bf9\u5916\u754c\u73af\u5883\u7684pH\u503c\u3001\u5149\u7167\u3001\u7535\u573a\u7b49\u56e0\u7d20\u505a\u51fa\u54cd\u5e94\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u901a\u5e38\u91c7\u7528\u591a\u5c42\u7ed3\u6784\u8bbe\u8ba1\uff0c\u5185\u5c42\u4e3a\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5916\u5c42\u4e3a\u667a\u80fd\u54cd\u5e94\u6750\u6599\uff0c\u80fd\u591f\u5728\u590d\u6742\u73af\u5883\u4e2d\u5b9e\u73b0\u7cbe\u51c6\u7684\u50ac\u5316\u63a7\u5236\u3002<\/p>\n<p><strong>\u5178\u578b\u4ea7\u54c1<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>pH\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578b\u50ac\u5316\u5242<\/strong>\uff1a\u5982Pd@PNIPAM-g-PMAA\uff0c\u9002\u7528\u4e8e\u9178\u78b1\u50ac\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578b\u50ac\u5316\u5242<\/strong>\uff1a\u5982Au@TiO\u2082\uff0c\u7528\u4e8e\u5149\u50ac\u5316\u548c\u70ed\u50ac\u5316\u8026\u5408\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong>\uff1a<\/th>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u5355\u4f4d<\/th>\n<th>\u5178\u578b\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6d3b\u5316\u6e29\u5ea6<\/td>\n<td>\u00b0C<\/td>\n<td>40-80<\/td>\n<\/tr>\n<tr>\n<td>\u54cd\u5e94\u65f6\u95f4<\/td>\n<td>\u79d2<\/td>\n<td>10-60<\/td>\n<\/tr>\n<tr>\n<td>\u7a33\u5b9a\u6027<\/td>\n<td>\u5c0f\u65f6<\/td>\n<td>&gt; 100 (\u5ba4\u6e29)<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u90e8\u523a\u6fc0<\/td>\n<td>&#8211;<\/td>\n<td>pH\u3001\u5149\u7167<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u5b9e\u9a8c\u8bbe\u8ba1\u4e0e\u65b9\u6cd5<\/h3>\n<p>\u4e3a\u4e86\u7cfb\u7edf\u5730\u7814\u7a76\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TDC\uff09\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u672c\u7814\u7a76\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u5b9e\u9a8c\uff0c\u6db5\u76d6\u4e86\u9ad8\u6e29\u3001\u4f4e\u6e29\u3001\u9ad8\u6e7f\u5ea6\u3001\u4f4e\u6e7f\u5ea6\u7b49\u591a\u79cd\u73af\u5883\u6761\u4ef6\u3002\u5b9e\u9a8c\u65e8\u5728\u8bc4\u4f30TDC\u7684\u50ac\u5316\u6d3b\u6027\u3001\u9009\u62e9\u6027\u3001\u7a33\u5b9a\u6027\u548c\u54cd\u5e94\u901f\u5ea6\uff0c\u4ee5\u63ed\u793a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u9002\u7528\u6027\u548c\u5c40\u9650\u6027\u3002\u4ee5\u4e0b\u662f\u5bf9\u5b9e\u9a8c\u8bbe\u8ba1\u548c\u65b9\u6cd5\u7684\u8be6\u7ec6\u8bf4\u660e\u3002<\/p>\n<h4>1. \u5b9e\u9a8c\u6750\u6599\u4e0e\u8bbe\u5907<\/h4>\n<p><strong>\u5b9e\u9a8c\u6750\u6599<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TDC\uff09<\/strong>\uff1a\u9009\u7528\u4e0a\u8ff0\u4e94\u79cd\u7c7b\u578b\u7684TDC\uff0c\u5206\u522b\u4e3a\u6709\u673a\u91d1\u5c5eTDC\u3001\u9176\u7c7bTDC\u3001\u7eb3\u7c73\u9897\u7c92TDC\u3001\u805a\u5408\u7269\u57faTDC\u548c\u667a\u80fd\u54cd\u5e94\u578bTDC\u3002<\/li>\n<li><strong>\u53cd\u5e94\u5e95\u7269<\/strong>\uff1a\u6839\u636e\u4e0d\u540c\u7684\u50ac\u5316\u53cd\u5e94\u7c7b\u578b\uff0c\u9009\u62e9\u76f8\u5e94\u7684\u5e95\u7269\uff0c\u5982\u70ef\u70c3\u3001\u919b\u7c7b\u3001\u916f\u7c7b\u3001\u8fc7\u6c27\u5316\u6c22\u7b49\u3002<\/li>\n<li><strong>\u6eb6\u5242<\/strong>\uff1a\u5e38\u7528\u6eb6\u5242\u5305\u62ec\u3001\u7532\u3001\u6c34\u7b49\uff0c\u5177\u4f53\u9009\u62e9\u53d6\u51b3\u4e8e\u53cd\u5e94\u4f53\u7cfb\u7684\u8981\u6c42\u3002<\/li>\n<li><strong>\u7f13\u51b2\u6eb6\u6db2<\/strong>\uff1a\u7528\u4e8e\u8c03\u8282pH\u503c\uff0c\u786e\u4fdd\u9176\u7c7bTDC\u5728\u9002\u5b9c\u7684pH\u8303\u56f4\u5185\u53d1\u6325\u4f5c\u7528\u3002<\/li>\n<\/ul>\n<p><strong>\u5b9e\u9a8c\u8bbe\u5907<\/strong>\uff1a<\/p>\n<ul>\n<li><strong>\u6052\u6e29\u6c34\u6d74\u9505<\/strong>\uff1a\u7528\u4e8e\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\uff0c\u7cbe\u5ea6\u00b10.1\u00b0C\u3002<\/li>\n<li><strong>\u6e7f\u5ea6\u63a7\u5236\u7bb1<\/strong>\uff1a\u7528\u4e8e\u6a21\u62df\u4e0d\u540c\u6e7f\u5ea6\u6761\u4ef6\uff0c\u8303\u56f40%-95%\u76f8\u5bf9\u6e7f\u5ea6\u3002<\/li>\n<li><strong>\u7d2b\u5916\u53ef\u89c1\u5206\u5149\u5149\u5ea6\u8ba1<\/strong>\uff1a\u7528\u4e8e\u76d1\u6d4b\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4ea7\u7269\u7684\u751f\u6210\u91cf\uff0c\u6ce2\u957f\u8303\u56f4200-800nm\u3002<\/li>\n<li><strong>\u6c14\u76f8\u8272\u8c31\u4eea\uff08GC\uff09<\/strong>\uff1a\u7528\u4e8e\u5206\u6790\u6c14\u4f53\u4ea7\u7269\u7684\u7ec4\u6210\u548c\u542b\u91cf\u3002<\/li>\n<li><strong>\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u4eea\uff08FTIR\uff09<\/strong>\uff1a\u7528\u4e8e\u8868\u5f81\u50ac\u5316\u5242\u7684\u7ed3\u6784\u53d8\u5316\u3002<\/li>\n<li><strong>\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09<\/strong>\uff1a\u7528\u4e8e\u89c2\u5bdf\u50ac\u5316\u5242\u7684\u5f62\u8c8c\u548c\u7c92\u5f84\u5206\u5e03\u3002<\/li>\n<\/ul>\n<h4>2. \u5b9e\u9a8c\u6761\u4ef6\u8bbe\u7f6e<\/h4>\n<p>\u4e3a\u4e86\u5168\u9762\u8bc4\u4f30TDC\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\uff0c\u5b9e\u9a8c\u8bbe\u7f6e\u4e86\u4ee5\u4e0b\u51e0\u4e2a\u5173\u952e\u53d8\u91cf\uff1a<\/p>\n<ul>\n<li><strong>\u6e29\u5ea6<\/strong>\uff1a\u5206\u522b\u5728\u4f4e\u6e29\uff080\u00b0C\uff09\u3001\u5e38\u6e29\uff0825\u00b0C\uff09\u3001\u9ad8\u6e29\uff0860\u00b0C\uff09\u6761\u4ef6\u4e0b\u8fdb\u884c\u5b9e\u9a8c\uff0c\u8003\u5bdfTDC\u7684\u6d3b\u5316\u6e29\u5ea6\u548c\u50ac\u5316\u6548\u7387\u968f\u6e29\u5ea6\u7684\u53d8\u5316\u3002<\/li>\n<li><strong>\u6e7f\u5ea6<\/strong>\uff1a\u901a\u8fc7\u6e7f\u5ea6\u63a7\u5236\u7bb1\u8c03\u8282\u76f8\u5bf9\u6e7f\u5ea6\uff0c\u5206\u522b\u5728\u4f4e\u6e7f\u5ea6\uff0810% RH\uff09\u3001\u4e2d\u6e7f\u5ea6\uff0850% RH\uff09\u3001\u9ad8\u6e7f\u5ea6\uff0890% RH\uff09\u6761\u4ef6\u4e0b\u8fdb\u884c\u5b9e\u9a8c\uff0c\u7814\u7a76\u6e7f\u5ea6\u5bf9TDC\u7a33\u5b9a\u6027\u7684\u5f71\u54cd\u3002<\/li>\n<li><strong>pH\u503c<\/strong>\uff1a\u5bf9\u4e8e\u9176\u7c7bTDC\u548c\u667a\u80fd\u54cd\u5e94\u578bTDC\uff0c\u8c03\u8282\u53cd\u5e94\u4f53\u7cfb\u7684pH\u503c\uff0c\u8303\u56f4\u4e3a3.0-9.0\uff0c\u8003\u5bdfpH\u503c\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u5f71\u54cd\u3002<\/li>\n<li><strong>\u5149\u7167\u5f3a\u5ea6<\/strong>\uff1a\u5bf9\u4e8e\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578bTDC\uff0c\u4f7f\u7528LED\u5149\u6e90\u6a21\u62df\u4e0d\u540c\u5149\u7167\u5f3a\u5ea6\uff080-1000 lux\uff09\uff0c\u7814\u7a76\u5149\u7167\u5bf9\u50ac\u5316\u53cd\u5e94\u7684\u4fc3\u8fdb\u4f5c\u7528\u3002<\/li>\n<\/ul>\n<h4>3. \u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p><strong>\u6b65\u9aa41\uff1a\u50ac\u5316\u5242\u9884\u5904\u7406<\/strong><\/p>\n<ul>\n<li>\u5bf9\u4e8e\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\uff0c\u4f7f\u7528\u8d85\u58f0\u6ce2\u5206\u6563\u6cd5\u5c06\u5176\u5747\u5300\u5206\u6563\u5728\u6eb6\u5242\u4e2d\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u60ac\u6d6e\u6db2\u3002<\/li>\n<li>\u5bf9\u4e8e\u9176\u7c7bTDC\uff0c\u4f7f\u7528\u7f13\u51b2\u6eb6\u6db2\u6eb6\u89e3\uff0c\u5e76\u901a\u8fc7\u79bb\u5fc3\u53bb\u9664\u4e0d\u6eb6\u6027\u6742\u8d28\u3002<\/li>\n<li>\u5bf9\u4e8e\u805a\u5408\u7269\u57faTDC\u548c\u667a\u80fd\u54cd\u5e94\u578bTDC\uff0c\u76f4\u63a5\u79f0\u53d6\u9002\u91cf\u6837\u54c1\uff0c\u52a0\u5165\u5230\u53cd\u5e94\u4f53\u7cfb\u4e2d\u3002<\/li>\n<\/ul>\n<p><strong>\u6b65\u9aa42\uff1a\u53cd\u5e94\u4f53\u7cfb\u6784\u5efa<\/strong><\/p>\n<ul>\n<li>\u6839\u636e\u5b9e\u9a8c\u8bbe\u8ba1\uff0c\u5c06\u5e95\u7269\u3001\u50ac\u5316\u5242\u548c\u6eb6\u5242\u6309\u4e00\u5b9a\u6bd4\u4f8b\u6df7\u5408\uff0c\u7f6e\u4e8e\u53cd\u5e94\u5bb9\u5668\u4e2d\u3002<\/li>\n<li>\u4f7f\u7528\u6052\u6e29\u6c34\u6d74\u9505\u548c\u6e7f\u5ea6\u63a7\u5236\u7bb1\u8c03\u8282\u53cd\u5e94\u6e29\u5ea6\u548c\u6e7f\u5ea6\uff0c\u786e\u4fdd\u5b9e\u9a8c\u6761\u4ef6\u7684\u7a33\u5b9a\u3002<\/li>\n<li>\u5bf9\u4e8e\u9700\u8981\u8c03\u8282pH\u503c\u7684\u5b9e\u9a8c\uff0c\u4f7f\u7528\u7f13\u51b2\u6eb6\u6db2\u8c03\u6574\u53cd\u5e94\u4f53\u7cfb\u7684pH\u503c\u81f3\u76ee\u6807\u503c\u3002<\/li>\n<\/ul>\n<p><strong>\u6b65\u9aa43\uff1a\u53cd\u5e94\u8fc7\u7a0b\u76d1\u6d4b<\/strong><\/p>\n<ul>\n<li>\u4f7f\u7528\u7d2b\u5916\u53ef\u89c1\u5206\u5149\u5149\u5ea6\u8ba1\u6216\u6c14\u76f8\u8272\u8c31\u4eea\u5b9e\u65f6\u76d1\u6d4b\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4ea7\u7269\u7684\u751f\u6210\u91cf\uff0c\u8bb0\u5f55\u53cd\u5e94\u65f6\u95f4\u548c\u8f6c\u5316\u7387\u3002<\/li>\n<li>\u5bf9\u4e8e\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578bTDC\uff0c\u4f7f\u7528LED\u5149\u6e90\u7167\u5c04\u53cd\u5e94\u4f53\u7cfb\uff0c\u540c\u65f6\u8bb0\u5f55\u5149\u7167\u5f3a\u5ea6\u548c\u53cd\u5e94\u901f\u7387\u7684\u53d8\u5316\u3002<\/li>\n<\/ul>\n<p><strong>\u6b65\u9aa44\uff1a\u50ac\u5316\u5242\u8868\u5f81<\/strong><\/p>\n<ul>\n<li>\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u4f7f\u7528FTIR\u548cSEM\u5bf9\u50ac\u5316\u5242\u8fdb\u884c\u8868\u5f81\uff0c\u5206\u6790\u5176\u7ed3\u6784\u53d8\u5316\u548c\u5f62\u8c8c\u7279\u5f81\u3002<\/li>\n<li>\u901a\u8fc7\u91cd\u590d\u4f7f\u7528\u5b9e\u9a8c\uff0c\u8bc4\u4f30\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u56de\u6536\u6027\u3002<\/li>\n<\/ul>\n<h4>4. \u6570\u636e\u5206\u6790\u65b9\u6cd5<\/h4>\n<p>\u4e3a\u4e86\u5b9a\u91cf\u5206\u6790TDC\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u5b9e\u9a8c\u91c7\u7528\u4e86\u4ee5\u4e0b\u51e0\u79cd\u6570\u636e\u5206\u6790\u65b9\u6cd5\uff1a<\/p>\n<ul>\n<li>\n<p><strong>\u50ac\u5316\u6548\u7387\u8ba1\u7b97<\/strong>\uff1a\u6839\u636e\u53cd\u5e94\u4ea7\u7269\u7684\u751f\u6210\u91cf\uff0c\u8ba1\u7b97\u50ac\u5316\u6548\u7387\uff08\u5355\u4f4d\u65f6\u95f4\u5185\u751f\u6210\u7684\u4ea7\u7269\u91cf\uff09\u3002\u516c\u5f0f\u5982\u4e0b\uff1a<br \/>\n[<br \/>\ntext{\u50ac\u5316\u6548\u7387} = frac{Delta C}{Delta t}<br \/>\n]<br \/>\n\u5176\u4e2d\uff0c(Delta C)\u8868\u793a\u4ea7\u7269\u6d53\u5ea6\u7684\u53d8\u5316\uff0c(Delta t)\u8868\u793a\u53cd\u5e94\u65f6\u95f4\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u9009\u62e9\u6027\u5206\u6790<\/strong>\uff1a\u901a\u8fc7\u6c14\u76f8\u8272\u8c31\u4eea\u5206\u6790\u53cd\u5e94\u4ea7\u7269\u7684\u7ec4\u6210\uff0c\u8ba1\u7b97\u76ee\u6807\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002\u516c\u5f0f\u5982\u4e0b\uff1a<br \/>\n[<br \/>\ntext{\u9009\u62e9\u6027} = frac{[\u76ee\u6807\u4ea7\u7269]}{[\u6240\u6709\u4ea7\u7269\u603b\u548c]} times 100%<br \/>\n]<\/p>\n<\/li>\n<li>\n<p><strong>\u7a33\u5b9a\u6027\u8bc4\u4f30<\/strong>\uff1a\u901a\u8fc7\u91cd\u590d\u4f7f\u7528\u5b9e\u9a8c\uff0c\u8bc4\u4f30\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u56de\u6536\u6027\u3002\u6bcf\u6b21\u5b9e\u9a8c\u540e\uff0c\u4f7f\u7528FTIR\u548cSEM\u5bf9\u50ac\u5316\u5242\u8fdb\u884c\u8868\u5f81\uff0c\u8bb0\u5f55\u5176\u7ed3\u6784\u53d8\u5316\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u54cd\u5e94\u901f\u5ea6\u6d4b\u5b9a<\/strong>\uff1a\u5bf9\u4e8e\u667a\u80fd\u54cd\u5e94\u578bTDC\uff0c\u8bb0\u5f55\u5176\u5728\u4e0d\u540c\u5916\u90e8\u523a\u6fc0\u4e0b\u7684\u54cd\u5e94\u65f6\u95f4\uff0c\u8bc4\u4f30\u5176\u54cd\u5e94\u901f\u5ea6\u3002\u54cd\u5e94\u65f6\u95f4\u5b9a\u4e49\u4e3a\u4ece\u65bd\u52a0\u523a\u6fc0\u5230\u50ac\u5316\u6d3b\u6027\u663e\u8457\u589e\u5f3a\u7684\u65f6\u95f4\u95f4\u9694\u3002<\/p>\n<\/li>\n<\/ul>\n<h3>\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0<\/h3>\n<p>\u901a\u8fc7\u5bf9\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TDC\uff09\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u5b9e\u9a8c\u7814\u7a76\uff0c\u6211\u4eec\u83b7\u5f97\u4e86\u5927\u91cf\u7684\u6570\u636e\uff0c\u63ed\u793a\u4e86TDC\u5728\u9ad8\u6e29\u3001\u4f4e\u6e29\u3001\u9ad8\u6e7f\u5ea6\u3001\u4f4e\u6e7f\u5ea6\u7b49\u73af\u5883\u4e2d\u7684\u6027\u80fd\u8868\u73b0\u3002\u4ee5\u4e0b\u662f\u5404\u7c7b\u578bTDC\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u8be6\u7ec6\u5206\u6790\u7ed3\u679c\u3002<\/p>\n<h4>1. \u6e29\u5ea6\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/h4>\n<p><strong>\u9ad8\u6e29\u6761\u4ef6\uff0860\u00b0C\uff09<\/strong>\uff1a<br \/>\n\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u6709\u673a\u91d1\u5c5eTDC\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u5347\uff0c\u5c24\u5176\u662fPd(II)\u914d\u5408\u7269\u548cRu(III)\u914d\u5408\u7269\u3002\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\uff0c\u914d\u4f53\u7684\u89e3\u79bb\u901f\u5ea6\u52a0\u5feb\uff0c\u66b4\u9732\u51fa\u66f4\u591a\u7684\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5bfc\u81f4\u50ac\u5316\u6548\u7387\u5927\u5e45\u63d0\u9ad8\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cPdCl\u2082(PPh\u2083)\u2082\u572860\u00b0C\u4e0b\u7684\u50ac\u5316\u6548\u7387\u8fbe\u5230\u4e8610\u207b\u2075 mol\/mol\uff0c\u8fdc\u9ad8\u4e8e\u5e38\u6e29\u6761\u4ef6\u4e0b\u768410\u207b\u2076 mol\/mol\u3002\u7136\u800c\uff0c\u9ad8\u6e29\u4e5f\u52a0\u901f\u4e86\u50ac\u5316\u5242\u7684\u5931\u6d3b\uff0c\u7279\u522b\u662f\u5728\u957f\u65f6\u95f4\u53cd\u5e94\u4e2d\uff0c\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u6709\u6240\u4e0b\u964d\u3002<\/p>\n<p>\u5bf9\u4e8e\u9176\u7c7bTDC\uff0c\u9ad8\u6e29\u5bf9\u5176\u50ac\u5316\u6d3b\u6027\u6709\u660e\u663e\u7684\u6291\u5236\u4f5c\u7528\u3002\u8102\u80aa\u9176\u548c\u8fc7\u6c27\u5316\u6c22\u9176\u572860\u00b0C\u4e0b\u7684\u6d3b\u6027\u6025\u5267\u4e0b\u964d\uff0c\u751a\u81f3\u5b8c\u5168\u5931\u6d3b\u3002\u8fd9\u662f\u7531\u4e8e\u9ad8\u6e29\u7834\u574f\u4e86\u9176\u7684\u4e09\u7ea7\u7ed3\u6784\uff0c\u5bfc\u81f4\u5176\u6d3b\u6027\u4e2d\u5fc3\u5931\u53bb\u529f\u80fd\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7eb3\u7c73\u9897\u7c92TDC\u548c\u805a\u5408\u7269\u57faTDC\u5728\u9ad8\u6e29\u4e0b\u8868\u73b0\u51fa\u8f83\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u5c24\u5176\u662f\u91d1\u7eb3\u7c73\u9897\u7c92\uff08Au NPs\uff09\u548c\u805aNIPAM\/Pd\u590d\u5408\u6750\u6599\uff0c\u5373\u4f7f\u572860\u00b0C\u4e0b\u4e5f\u80fd\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6548\u7387\u3002<\/p>\n<p><strong>\u4f4e\u6e29\u6761\u4ef6\uff080\u00b0C\uff09<\/strong>\uff1a<br \/>\n\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u5927\u591a\u6570TDC\u7684\u50ac\u5316\u6d3b\u6027\u663e\u8457\u964d\u4f4e\uff0c\u5c24\u5176\u662f\u9176\u7c7bTDC\u548c\u667a\u80fd\u54cd\u5e94\u578bTDC\u3002\u4f4e\u6e29\u51cf\u7f13\u4e86\u5206\u5b50\u8fd0\u52a8\u548c\u6269\u6563\u901f\u5ea6\uff0c\u5bfc\u81f4\u53cd\u5e94\u901f\u7387\u4e0b\u964d\u3002\u4f8b\u5982\uff0c\u8102\u80aa\u9176\u57280\u00b0C\u4e0b\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e3a\u5e38\u6e29\u6761\u4ef6\u4e0b\u768420%\uff0c\u800cpH\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578b\u50ac\u5316\u5242Pd@PNIPAM-g-PMAA\u7684\u54cd\u5e94\u65f6\u95f4\u5ef6\u957f\u81f360\u79d2\u4ee5\u4e0a\uff0c\u8fdc\u9ad8\u4e8e\u5e38\u6e29\u6761\u4ef6\u4e0b\u768410\u79d2\u3002<\/p>\n<p>\u7136\u800c\uff0c\u67d0\u4e9b\u7c7b\u578b\u7684TDC\u5728\u4f4e\u6e29\u4e0b\u4ecd\u8868\u73b0\u51fa\u4e00\u5b9a\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u6709\u673a\u91d1\u5c5eTDC\u4e2d\u7684RuCl\u2083\u00b7xH\u2082O\u57280\u00b0C\u4e0b\u4ecd\u7136\u80fd\u591f\u6709\u6548\u50ac\u5316\u7fb0\u57fa\u5316\u5408\u7269\u7684\u8fd8\u539f\u53cd\u5e94\uff0c\u50ac\u5316\u6548\u7387\u8fbe\u523010\u207b\u2075 mol\/mol\u3002\u6b64\u5916\uff0c\u7eb3\u7c73\u9897\u7c92TDC\u4e2d\u7684TiO\u2082 NPs\u5728\u4f4e\u6e29\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u50ac\u5316\u6027\u80fd\uff0c\u5c3d\u7ba1\u5176\u70ed\u50ac\u5316\u6d3b\u6027\u8f83\u4f4e\u3002<\/p>\n<p><strong>\u5e38\u6e29\u6761\u4ef6\uff0825\u00b0C\uff09<\/strong>\uff1a<br \/>\n\u5728\u5e38\u6e29\u6761\u4ef6\u4e0b\uff0cTDC\u7684\u8868\u73b0\u4e3a\u7a33\u5b9a\uff0c\u5404\u7c7b\u50ac\u5316\u5242\u5747\u80fd\u5728\u9002\u5b9c\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u53d1\u6325\u4f73\u50ac\u5316\u6548\u679c\u3002\u6709\u673a\u91d1\u5c5eTDC\u3001\u9176\u7c7bTDC\u3001\u7eb3\u7c73\u9897\u7c92TDC\u548c\u805a\u5408\u7269\u57faTDC\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u8fbe\u5230\u4e8610\u207b\u2076 mol\/mol\u3001100 U\/mg\u300110\u207b\u2075 mol\/mol\u548c10\u207b\u2076 mol\/mol\u3002\u667a\u80fd\u54cd\u5e94\u578bTDC\u5728\u5e38\u6e29\u4e0b\u7684\u54cd\u5e94\u65f6\u95f4\u77ed\uff0cPd@PNIPAM-g-PMAA\u7684\u54cd\u5e94\u65f6\u95f4\u4e3a10\u79d2\uff0c\u663e\u793a\u51fa\u5feb\u901f\u7684\u6e29\u5ea6\u54cd\u5e94\u7279\u6027\u3002<\/p>\n<h4>2. \u6e7f\u5ea6\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/h4>\n<p><strong>\u9ad8\u6e7f\u5ea6\u6761\u4ef6\uff0890% RH\uff09<\/strong>\uff1a<br \/>\n\u5728\u9ad8\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0c\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u53d7\u5230\u663e\u8457\u5f71\u54cd\uff0c\u5c24\u5176\u662f\u8102\u80aa\u9176\u548c\u8fc7\u6c27\u5316\u6c22\u9176\u3002\u9ad8\u6e7f\u5ea6\u4f1a\u5bfc\u81f4\u9176\u7684\u5438\u6c34\u81a8\u80c0\uff0c\u7834\u574f\u5176\u7a7a\u95f4\u7ed3\u6784\uff0c\u8fdb\u800c\u964d\u4f4e\u50ac\u5316\u6548\u7387\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u8102\u80aa\u9176\u572890% RH\u4e0b\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e3a50 U\/mg\uff0c\u8fdc\u4f4e\u4e8e\u5e38\u6e7f\u6761\u4ef6\u4e0b\u7684100 U\/mg\u3002\u6b64\u5916\uff0c\u9ad8\u6e7f\u5ea6\u8fd8\u4f1a\u52a0\u901f\u9176\u7684\u964d\u89e3\uff0c\u7f29\u77ed\u5176\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n<p>\u5bf9\u4e8e\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\uff0c\u9ad8\u6e7f\u5ea6\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u572890% RH\u4e0b\u7684\u50ac\u5316\u6548\u7387\u57fa\u672c\u4fdd\u6301\u4e0d\u53d8\uff0c\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\u3002\u7136\u800c\uff0c\u9ad8\u6e7f\u5ea6\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u56e2\u805a\u73b0\u8c61\uff0c\u5f71\u54cd\u5176\u5206\u6563\u6027\u548c\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cAu NPs\u572890% RH\u4e0b\u7684\u7c92\u5f84\u7565\u6709\u589e\u5927\uff0c\u5bfc\u81f4\u5176\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong>\u4f4e\u6e7f\u5ea6\u6761\u4ef6\uff0810% RH\uff09<\/strong>\uff1a<br \/>\n\u5728\u4f4e\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0c\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u540c\u6837\u53d7\u5230\u5f71\u54cd\uff0c\u4f46\u4e0e\u9ad8\u6e7f\u5ea6\u76f8\u53cd\uff0c\u4f4e\u6e7f\u5ea6\u4f1a\u5bfc\u81f4\u9176\u7684\u8131\u6c34\u6536\u7f29\uff0c\u5f71\u54cd\u5176\u6d3b\u6027\u4e2d\u5fc3\u7684\u529f\u80fd\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u8102\u80aa\u9176\u572810% RH\u4e0b\u7684\u50ac\u5316\u6548\u7387\u964d\u81f330 U\/mg\uff0c\u8fc7\u6c27\u5316\u6c22\u9176\u7684\u50ac\u5316\u6548\u7387\u4e5f\u6709\u6240\u4e0b\u964d\u3002\u6b64\u5916\uff0c\u4f4e\u6e7f\u5ea6\u8fd8\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u5e95\u7269\u7684\u6eb6\u89e3\u5ea6\u964d\u4f4e\uff0c\u8fdb\u4e00\u6b65\u5f71\u54cd\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<p>\u5bf9\u4e8e\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\uff0c\u4f4e\u6e7f\u5ea6\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u572810% RH\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\uff0c\u4e0e\u5e38\u6e7f\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\u76f8\u8fd1\u3002\u7136\u800c\uff0c\u4f4e\u6e7f\u5ea6\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u5438\u9644\u6c34\u5206\u51cf\u5c11\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cTiO\u2082 NPs\u572810% RH\u4e0b\u7684\u5149\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong>\u4e2d\u6e7f\u5ea6\u6761\u4ef6\uff0850% RH\uff09<\/strong>\uff1a<br \/>\n\u5728\u4e2d\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0cTDC\u7684\u8868\u73b0\u4e3a\u7a33\u5b9a\uff0c\u5404\u7c7b\u50ac\u5316\u5242\u5747\u80fd\u5728\u9002\u5b9c\u7684\u6e7f\u5ea6\u8303\u56f4\u5185\u53d1\u6325\u4f73\u50ac\u5316\u6548\u679c\u3002\u9176\u7c7bTDC\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a100 U\/mg\u548c500 U\/mg\uff0c\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\u3002\u667a\u80fd\u54cd\u5e94\u578bTDC\u5728\u4e2d\u6e7f\u5ea6\u4e0b\u7684\u54cd\u5e94\u65f6\u95f4\u77ed\uff0cPd@PNIPAM-g-PMAA\u7684\u54cd\u5e94\u65f6\u95f4\u4e3a10\u79d2\uff0c\u663e\u793a\u51fa\u5feb\u901f\u7684\u6e7f\u5ea6\u54cd\u5e94\u7279\u6027\u3002<\/p>\n<h4>3. pH\u503c\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/h4>\n<p><strong>\u9178\u6027\u6761\u4ef6\uff08pH 3.0\uff09<\/strong>\uff1a<br \/>\n\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u53d7\u5230\u663e\u8457\u6291\u5236\uff0c\u5c24\u5176\u662f\u8fc7\u6c27\u5316\u6c22\u9176\u3002\u9178\u6027\u73af\u5883\u4f1a\u7834\u574f\u9176\u7684\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5bfc\u81f4\u5176\u5931\u6d3b\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u8fc7\u6c27\u5316\u6c22\u9176\u5728pH 3.0\u4e0b\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e3a10 U\/mg\uff0c\u8fdc\u4f4e\u4e8e\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684500 U\/mg\u3002\u6b64\u5916\uff0c\u9178\u6027\u73af\u5883\u8fd8\u4f1a\u5f71\u54cd\u67d0\u4e9b\u5e95\u7269\u7684\u7a33\u5b9a\u6027\uff0c\u5bfc\u81f4\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n<p>\u5bf9\u4e8e\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\uff0c\u9178\u6027\u6761\u4ef6\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u5728pH 3.0\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\uff0c\u4e0e\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\u76f8\u8fd1\u3002\u7136\u800c\uff0c\u9178\u6027\u73af\u5883\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u4fee\u9970\u57fa\u56e2\u53d1\u751f\u53d8\u5316\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cTiO\u2082 NPs\u5728pH 3.0\u4e0b\u7684\u5149\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong>\u78b1\u6027\u6761\u4ef6\uff08pH 9.0\uff09<\/strong>\uff1a<br \/>\n\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u540c\u6837\u53d7\u5230\u5f71\u54cd\uff0c\u5c24\u5176\u662f\u8102\u80aa\u9176\u3002\u78b1\u6027\u73af\u5883\u4f1a\u7834\u574f\u9176\u7684\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5bfc\u81f4\u5176\u5931\u6d3b\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u8102\u80aa\u9176\u5728pH 9.0\u4e0b\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e3a30 U\/mg\uff0c\u8fdc\u4f4e\u4e8e\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684100 U\/mg\u3002\u6b64\u5916\uff0c\u78b1\u6027\u73af\u5883\u8fd8\u4f1a\u5f71\u54cd\u67d0\u4e9b\u5e95\u7269\u7684\u7a33\u5b9a\u6027\uff0c\u5bfc\u81f4\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n<p>\u5bf9\u4e8e\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\uff0c\u78b1\u6027\u6761\u4ef6\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u5728pH 9.0\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\uff0c\u4e0e\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\u76f8\u8fd1\u3002\u7136\u800c\uff0c\u78b1\u6027\u73af\u5883\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u4fee\u9970\u57fa\u56e2\u53d1\u751f\u53d8\u5316\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cTiO\u2082 NPs\u5728pH 9.0\u4e0b\u7684\u5149\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong>\u4e2d\u6027\u6761\u4ef6\uff08pH 7.0-8.5\uff09<\/strong>\uff1a<br \/>\n\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\uff0cTDC\u7684\u8868\u73b0\u4e3a\u7a33\u5b9a\uff0c\u5404\u7c7b\u50ac\u5316\u5242\u5747\u80fd\u5728\u9002\u5b9c\u7684pH\u8303\u56f4\u5185\u53d1\u6325\u4f73\u50ac\u5316\u6548\u679c\u3002\u9176\u7c7bTDC\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a100 U\/mg\u548c500 U\/mg\uff0c\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\u3002\u667a\u80fd\u54cd\u5e94\u578bTDC\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u54cd\u5e94\u65f6\u95f4\u77ed\uff0cPd@PNIPAM-g-PMAA\u7684\u54cd\u5e94\u65f6\u95f4\u4e3a10\u79d2\uff0c\u663e\u793a\u51fa\u5feb\u901f\u7684pH\u54cd\u5e94\u7279\u6027\u3002<\/p>\n<h4>4. \u5149\u7167\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/h4>\n<p><strong>\u5f3a\u5149\u7167\u6761\u4ef6\uff081000 lux\uff09<\/strong>\uff1a<br \/>\n\u5728\u5f3a\u5149\u7167\u6761\u4ef6\u4e0b\uff0c\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578bTDC\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u5347\uff0c\u5c24\u5176\u662fAu@TiO\u2082\u3002\u5149\u7167\u4fc3\u8fdb\u4e86\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u5206\u79bb\uff0c\u589e\u5f3a\u4e86\u50ac\u5316\u5242\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u5bfc\u81f4\u50ac\u5316\u6548\u7387\u5927\u5e45\u63d0\u9ad8\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cAu@TiO\u2082\u57281000 lux\u4e0b\u7684\u50ac\u5316\u6548\u7387\u8fbe\u5230\u4e8610\u207b\u2074 mol\/mol\uff0c\u8fdc\u9ad8\u4e8e\u65e0\u5149\u7167\u6761\u4ef6\u4e0b\u768410\u207b\u2075 mol\/mol\u3002\u6b64\u5916\uff0c\u5f3a\u5149\u7167\u8fd8\u52a0\u901f\u4e86\u67d0\u4e9b\u5e95\u7269\u7684\u5206\u89e3\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<p>\u5bf9\u4e8e\u5176\u4ed6\u7c7b\u578b\u7684TDC\uff0c\u5149\u7167\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u57281000 lux\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\uff0c\u4e0e\u65e0\u5149\u7167\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\u76f8\u8fd1\u3002\u7136\u800c\uff0c\u5f3a\u5149\u7167\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u4fee\u9970\u57fa\u56e2\u53d1\u751f\u53d8\u5316\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cTiO\u2082 NPs\u57281000 lux\u4e0b\u7684\u5149\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<p><strong>\u5f31\u5149\u7167\u6761\u4ef6\uff080 lux\uff09<\/strong>\uff1a<br \/>\n\u5728\u5f31\u5149\u7167\u6761\u4ef6\u4e0b\uff0c\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578bTDC\u7684\u50ac\u5316\u6d3b\u6027\u663e\u8457\u964d\u4f4e\uff0c\u5c24\u5176\u662fAu@TiO\u2082\u3002\u7f3a\u4e4f\u5149\u7167\u5bfc\u81f4\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u5206\u79bb\u6548\u7387\u964d\u4f4e\uff0c\u524a\u5f31\u4e86\u50ac\u5316\u5242\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u5bfc\u81f4\u50ac\u5316\u6548\u7387\u4e0b\u964d\u3002\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0cAu@TiO\u2082\u57280 lux\u4e0b\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e3a10\u207b\u2075 mol\/mol\uff0c\u8fdc\u4f4e\u4e8e\u5f3a\u5149\u7167\u6761\u4ef6\u4e0b\u768410\u207b\u2074 mol\/mol\u3002\u6b64\u5916\uff0c\u5f31\u5149\u7167\u8fd8\u53ef\u80fd\u5bfc\u81f4\u67d0\u4e9b\u5e95\u7269\u7684\u5206\u89e3\u901f\u7387\u964d\u4f4e\uff0c\u5f71\u54cd\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<p>\u5bf9\u4e8e\u5176\u4ed6\u7c7b\u578b\u7684TDC\uff0c\u5f31\u5149\u7167\u5bf9\u5176\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u8f83\u5c0f\u3002PdCl\u2082(PPh\u2083)\u2082\u548cRuCl\u2083\u00b7xH\u2082O\u57280 lux\u4e0b\u7684\u50ac\u5316\u6548\u7387\u5206\u522b\u4e3a10\u207b\u2076 mol\/mol\u548c10\u207b\u2075 mol\/mol\uff0c\u4e0e\u5f3a\u5149\u7167\u6761\u4ef6\u4e0b\u7684\u8868\u73b0\u76f8\u8fd1\u3002\u7136\u800c\uff0c\u5f31\u5149\u7167\u53ef\u80fd\u4f1a\u5bfc\u81f4\u67d0\u4e9b\u7eb3\u7c73\u9897\u7c92\u7684\u8868\u9762\u4fee\u9970\u57fa\u56e2\u53d1\u751f\u53d8\u5316\uff0c\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0cTiO\u2082 NPs\u57280 lux\u4e0b\u7684\u5149\u50ac\u5316\u6548\u7387\u7565\u6709\u4e0b\u964d\u3002<\/p>\n<h3>\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h3>\n<p>\u901a\u8fc7\u5bf9\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TDC\uff09\u5728\u4e0d\u540c\u6c14\u5019\u6761\u4ef6\u4e0b\u7684\u7cfb\u7edf\u7814\u7a76\uff0c\u6211\u4eec\u5f97\u51fa\u4e86\u4ee5\u4e0b\u7ed3\u8bba\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u6e29\u5ea6\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/strong>\uff1a\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u5347\uff0c\u4f46\u9ad8\u6e29\u4e5f\u4f1a\u52a0\u901f\u50ac\u5316\u5242\u7684\u5931\u6d3b\uff1b\u9176\u7c7bTDC\u5728\u9ad8\u6e29\u4e0b\u5931\u6d3b\u4e25\u91cd\uff0c\u9002\u5408\u5728\u4f4e\u6e29\u6216\u5e38\u6e29\u6761\u4ef6\u4e0b\u4f7f\u7528\uff1b\u667a\u80fd\u54cd\u5e94\u578bTDC\u5728\u5e38\u6e29\u4e0b\u8868\u73b0\u51fa\u4f73\u7684\u6e29\u5ea6\u54cd\u5e94\u7279\u6027\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u6e7f\u5ea6\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/strong>\uff1a\u9ad8\u6e7f\u5ea6\u548c\u4f4e\u6e7f\u5ea6\u90fd\u4f1a\u5bf9\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u4ea7\u751f\u8d1f\u9762\u5f71\u54cd\uff0c\u800c\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\u5728\u4e2d\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u8868\u73b0\u4e3a\u7a33\u5b9a\uff1b\u6e7f\u5ea6\u5bf9\u667a\u80fd\u54cd\u5e94\u578bTDC\u7684\u54cd\u5e94\u901f\u5ea6\u6709\u663e\u8457\u5f71\u54cd\uff0c\u4e2d\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u54cd\u5e94\u5feb\u3002<\/p>\n<\/li>\n<li>\n<p><strong>pH\u503c\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/strong>\uff1a\u9178\u6027\u548c\u78b1\u6027\u6761\u4ef6\u90fd\u4f1a\u5bf9\u9176\u7c7bTDC\u7684\u50ac\u5316\u6d3b\u6027\u4ea7\u751f\u6291\u5236\u4f5c\u7528\uff0c\u800c\u6709\u673a\u91d1\u5c5eTDC\u548c\u7eb3\u7c73\u9897\u7c92TDC\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\u8868\u73b0\u4e3a\u7a33\u5b9a\uff1bpH\u503c\u5bf9\u667a\u80fd\u54cd\u5e94\u578bTDC\u7684\u54cd\u5e94\u901f\u5ea6\u6709\u663e\u8457\u5f71\u54cd\uff0c\u4e2d\u6027\u6761\u4ef6\u4e0b\u54cd\u5e94\u5feb\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5149\u7167\u5bf9TDC\u6027\u80fd\u7684\u5f71\u54cd<\/strong>\uff1a\u5f3a\u5149\u7167\u6761\u4ef6\u4e0b\uff0c\u5149\/\u6e29\u5ea6\u53cc\u54cd\u5e94\u578bTDC\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u5347\uff0c\u800c\u5f31\u5149\u7167\u5219\u4f1a\u663e\u8457\u964d\u4f4e\u5176\u50ac\u5316\u6548\u7387\uff1b\u5149\u7167\u5bf9\u5176\u4ed6\u7c7b\u578b\u7684TDC\u5f71\u54cd\u8f83\u5c0f\uff0c\u4f46\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\u53ef\u80fd\u4f1a\u5f71\u54cd\u5176\u8868\u9762\u4fee\u9970\u57fa\u56e2\uff0c\u8fdb\u800c\u5f71\u54cd\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<\/li>\n<\/ol>\n<p>\u57fa\u4e8e\u4ee5\u4e0a\u7814\u7a76\u7ed3\u679c\uff0c\u6211\u4eec\u53ef\u4ee5\u5f97\u51fa\u4ee5\u4e0b\u51e0\u70b9\u5c55\u671b\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u5f00\u53d1\u65b0\u578bTDC\u6750\u6599<\/strong>\uff1a\u672a\u6765\u7684\u7814\u7a76\u5e94\u81f4\u529b\u4e8e\u5f00\u53d1\u5177\u6709\u66f4\u9ad8\u70ed\u7a33\u5b9a\u6027\u548c\u66f4\u5bbd\u6e29\u5ea6\u54cd\u5e94\u8303\u56f4\u7684TDC\u6750\u6599\uff0c\u4ee5\u6ee1\u8db3\u4e0d\u540c\u5e94\u7528\u573a\u666f\u7684\u9700\u6c42\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u9176\u7c7bTDC\uff0c\u53ef\u4ee5\u901a\u8fc7\u57fa\u56e0\u5de5\u7a0b\u624b\u6bb5\u4f18\u5316\u5176\u70ed\u7a33\u5b9a\u6027\u548cpH\u9002\u5e94\u6027\uff0c\u6269\u5927\u5176\u5e94\u7528\u9886\u57df\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u4f18\u5316TDC\u7ed3\u6784\u8bbe\u8ba1<\/strong>\uff1a\u901a\u8fc7\u5f15\u5165\u591a\u529f\u80fd\u54cd\u5e94\u5355\u5143\uff0c\u5f00\u53d1\u667a\u80fd\u54cd\u5e94\u578bTDC\uff0c\u4f7f\u5176\u80fd\u591f\u5728\u6e29\u5ea6\u3001\u6e7f\u5ea6\u3001pH\u503c\u3001\u5149\u7167\u7b49\u591a\u79cd\u5916\u754c\u523a\u6fc0\u4e0b\u5b9e\u73b0\u7cbe\u51c6\u7684\u50ac\u5316\u63a7\u5236\u3002\u8fd9\u5c06\u6709\u52a9\u4e8e\u63d0\u9ad8TDC\u7684\u9002\u5e94\u6027\u548c\u7075\u6d3b\u6027\uff0c\u62d3\u5c55\u5176\u5728\u590d\u6742\u73af\u5883\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u63a2\u7d22TDC\u5728\u65b0\u5174\u9886\u57df\u7684\u5e94\u7528<\/strong>\uff1a\u968f\u7740\u5bf9\u50ac\u5316\u53cd\u5e94\u63a7\u5236\u9700\u6c42\u7684\u589e\u52a0\uff0cTDC\u5728\u80fd\u6e90\u3001\u73af\u5883\u3001\u533b\u836f\u7b49\u9886\u57df\u7684\u5e94\u7528\u524d\u666f\u5e7f\u9614\u3002\u4f8b\u5982\uff0cTDC\u53ef\u4ee5\u7528\u4e8e\u5f00\u53d1\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5242\uff0c\u4fc3\u8fdb\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\uff1b\u4e5f\u53ef\u4ee5\u7528\u4e8e\u5f00\u53d1\u667a\u80fd\u836f\u7269\u9012\u9001\u7cfb\u7edf\uff0c\u5b9e\u73b0\u836f\u7269\u7684\u7cbe\u51c6\u91ca\u653e\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u52a0\u5f3a\u57fa\u7840\u7406\u8bba\u7814\u7a76<\/strong>\uff1a\u5c3d\u7ba1TDC\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u8fdb\u5c55\uff0c\u4f46\u5176\u5fae\u89c2\u673a\u5236\u4ecd\u6709\u5f85\u6df1\u5165\u7814\u7a76\u3002\u672a\u6765\u7684\u7814\u7a76\u5e94\u52a0\u5f3a\u5bf9TDC\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u91cf\u5b50\u5316\u5b66\u8ba1\u7b97\uff0c\u63ed\u793a\u5176\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u6784\u6548\u5173\u7cfb\uff0c\u4e3a\u8bbe\u8ba1\u66f4\u9ad8\u6548\u7684TDC\u63d0\u4f9b\u7406\u8bba\u652f\u6301\u3002<\/p>\n<\/li>\n<\/ol>\n<p>\u603b\u4e4b\uff0c\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u4f5c\u4e3a\u4e00\u79cd\u5177\u6709\u72ec\u7279\u6e29\u5ea6\u54cd\u5e94\u7279\u6027\u7684\u50ac\u5316\u6750\u6599\uff0c\u5df2\u7ecf\u5728\u591a\u4e2a\u9886\u57df\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u901a\u8fc7\u4e0d\u65ad\u4f18\u5316\u5176\u6750\u6599\u7ed3\u6784\u548c\u6027\u80fd\uff0cTDC\u6709\u671b\u5728\u672a\u6765\u7684\u6280\u672f\u521b\u65b0\u4e2d\u53d1\u6325\u66f4\u52a0\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/borchi-kat-28-cas-301-10-0\/\">https:\/\/www.cyclohexylamine.net\/borchi-kat-28-cas-301-10-0\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/40287\">https:\/\/www.newtopchem.com\/archives\/40287<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1103\">https:\/\/www.newtopchem.com\/archives\/1103<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/45191\">https:\/\/www.newtopchem.com\/archives\/45191<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/38903\">https:\/\/www.newtopchem.com\/archives\/38903<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/high-quality-nn-dicyclohexylmethylamine-cas-7560-83-0\/\">https:\/\/www.bdmaee.net\/high-quality-nn-dicyclohexylmethylamine-cas-7560-83-0\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-pt305-low-odor-reactive-amine-catalyst-pt305\/\">https:\/\/www.cyclohexylamine.net\/dabco-pt305-low-odor-reactive-amine-catalyst-pt305\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/di-n-butyl-tin-diisooctoate-cas2781-10-4-fascat4208-catalyst\/\">https:\/\/www.bdmaee.net\/di-n-butyl-tin-diisooctoate-cas2781-10-4-fascat4208-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.morpholine.org\/polyurethane-blowing-catalyst-blowing-catalyst\/\">https:\/\/www.morpholine.org\/polyurethane-blowing-catalyst-blowing-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/tris3-dimethylaminopropylamine\/\">https:\/\/www.bdmaee.net\/tris3-dimethylaminopropylamine\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u7684\u6982\u8ff0 \u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08Thermosensitive Delayed Catalyst, TDC\uff09\u662f\u4e00\u7c7b\u80fd\u591f\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u89e6\u53d1\u5316\u5b66\u53cd\u5e94\u6216\u6539\u53d8\u53cd\u5e94\u901f\u7387\u7684\u50ac\u5316\u5242\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5316\u5de5\u3001\u5236\u836f\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\uff0c\u5c24\u5176\u662f\u5728\u9700\u8981\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u65f6\u95f4\u6216\u6e29\u5ea6\u6761\u4ef6\u7684\u60c5\u51b5\u4e0b\u3002\u4e0e\u4f20\u7edf\u7684\u50ac\u5316\u5242\u76f8\u6bd4\uff0cTDC\u7684\u5927\u7279\u70b9\u662f\u5176\u6d3b\u6027\u53d7\u5230\u6e29 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[2234],"_links":{"self":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6211"}],"collection":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/comments?post=6211"}],"version-history":[{"count":0,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/posts\/6211\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/media?parent=6211"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/categories?post=6211"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.xindianchem.com\/wp-json\/wp\/v2\/tags?post=6211"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}