{"id":6458,"date":"2025-02-20T20:45:30","date_gmt":"2025-02-20T12:45:30","guid":{"rendered":"https:\/\/www.xindianchem.com\/6458.html"},"modified":"2025-02-20T20:45:30","modified_gmt":"2025-02-20T12:45:30","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e4%b9%99%e4%ba%8c%e8%83%ba%ef%bc%9a%e7%a7%91%e5%ad%a6%e6%8e%a2%e7%b4%a2%e4%b8%ad%e7%9a%84%e7%92%80%e7%92%a8%e4%b9%8b%e6%98%9f%ef%bc%8c%e6%8c%87%e5%bc%95%e5%89%8d%e8%a1%8c","status":"publish","type":"post","link":"https:\/\/www.xindianchem.com\/6458.html","title":{"rendered":"\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff1a\u79d1\u5b66\u63a2\u7d22\u4e2d\u7684\u7480\u74a8\u4e4b\u661f\uff0c\u6307\u5f15\u524d\u884c\u65b9\u5411"},"content":{"rendered":"

\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff1a\u5316\u5b66\u4e16\u754c\u4e2d\u7684\u7480\u74a8\u660e\u661f<\/h3>\n

\u5728\u5316\u5b66\u7684\u5e7f\u9614\u5929\u5730\u4e2d\uff0c\u6709\u65e0\u6570\u5316\u5408\u7269\u4ee5\u5176\u72ec\u7279\u7684\u6027\u8d28\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u800c\u95ea\u8000\u3002\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08Tetramethylethylenediamine, TMEDA\uff09\uff0c\u4fbf\u662f\u5176\u4e2d\u4e00\u9897\u7480\u74a8\u7684\u660e\u661f\u3002\u5b83\u662f\u4e00\u79cd\u6709\u673a\u5316\u5408\u7269\uff0c\u5206\u5b50\u5f0f\u4e3aC6H16N2\uff0c\u5c5e\u4e8e\u8102\u80aa\u65cf\u80fa\u7c7b\u5316\u5408\u7269\u3002TMEDA\u56e0\u5176\u7279\u6b8a\u7684\u7ed3\u6784\u548c\u529f\u80fd\uff0c\u5728\u79d1\u5b66\u7814\u7a76\u548c\u5de5\u4e1a\u5e94\u7528\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002<\/p>\n

\u521d\u8bc6\u56db\u7532\u57fa\u4e59\u4e8c\u80fa<\/h4>\n

\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff0c\u5982\u540c\u4e00\u4f4d\u8eab\u6000\u7edd\u6280\u7684\u6b66\u6797\u9ad8\u624b\uff0c\u5176\u5206\u5b50\u7ed3\u6784\u72ec\u7279\uff0c\u7531\u4e24\u4e2a\u7532\u57fa\u53d6\u4ee3\u7684\u4e59\u4e8c\u80fa\u5355\u5143\u7ec4\u6210\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u5f3a\u5927\u7684\u914d\u4f4d\u80fd\u529b\u548c\u53cd\u5e94\u6d3b\u6027\uff0c\u4f7f\u5176\u6210\u4e3a\u8bb8\u591a\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u7406\u60f3\u50ac\u5316\u5242\u6216\u914d\u4f53\u3002\u60f3\u8c61\u4e00\u4e0b\uff0c\u5982\u679c\u5c06\u6bcf\u4e2a\u539f\u5b50\u770b\u4f5c\u662f\u5efa\u7b51\u4e2d\u7684\u7816\u5757\uff0c\u90a3\u4e48TMEDA\u5c31\u662f\u4e00\u5ea7\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u5927\u53a6\uff0c\u6bcf\u4e00\u4e2a\u90e8\u5206\u90fd\u7cbe\u786e\u5730\u53d1\u6325\u7740\u81ea\u5df1\u7684\u4f5c\u7528\u3002<\/p>\n

\u5316\u5b66\u754c\u7684\u591a\u9762\u624b<\/h4>\n

TMEDA\u4e0d\u4ec5\u4ec5\u662f\u4e00\u4e2a\u666e\u901a\u7684\u5316\u5408\u7269\uff0c\u5b83\u66f4\u50cf\u662f\u4e00\u4f4d\u591a\u624d\u591a\u827a\u7684\u827a\u672f\u5bb6\uff0c\u80fd\u5728\u4e0d\u540c\u7684\u573a\u5408\u5c55\u73b0\u51fa\u4e0d\u540c\u7684\u98ce\u91c7\u3002\u5728\u5b9e\u9a8c\u5ba4\u91cc\uff0c\u5b83\u662f\u79d1\u7814\u4eba\u5458\u7684\u597d\u5e2e\u624b\uff1b\u5728\u5de5\u4e1a\u751f\u4ea7\u7ebf\u4e0a\uff0c\u5b83\u662f\u63d0\u9ad8\u6548\u7387\u7684\u5173\u952e\u5de5\u5177\u3002\u65e0\u8bba\u662f\u4f5c\u4e3a\u50ac\u5316\u5242\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\uff0c\u8fd8\u662f\u4f5c\u4e3a\u7a33\u5b9a\u5242\u5ef6\u957f\u4ea7\u54c1\u7684\u5bff\u547d\uff0cTMEDA\u90fd\u80fd\u51fa\u8272\u5730\u5b8c\u6210\u4efb\u52a1\u3002<\/p>\n

\u79d1\u5b66\u63a2\u7d22\u4e2d\u7684\u5bfc\u822a\u661f<\/h4>\n

\u6b63\u5982\u591c\u7a7a\u4e2d\u4eae\u7684\u661f\u661f\u6307\u5f15\u7740\u822a\u6d77\u8005\u7684\u65b9\u5411\uff0cTMEDA\u4e5f\u5728\u79d1\u5b66\u63a2\u7d22\u7684\u9053\u8def\u4e0a\u4e3a\u7814\u7a76\u8005\u4eec\u63d0\u4f9b\u6307\u5f15\u3002\u5b83\u7684\u5b58\u5728\u4e0d\u4ec5\u63a8\u52a8\u4e86\u65b0\u6750\u6599\u7684\u7814\u53d1\uff0c\u4e5f\u4fc3\u8fdb\u4e86\u65b0\u5de5\u827a\u7684\u8bde\u751f\u3002\u5728\u8fd9\u4e2a\u5145\u6ee1\u6311\u6218\u4e0e\u673a\u9047\u7684\u65f6\u4ee3\uff0cTMEDA\u65e0\u7591\u6210\u4e3a\u4e86\u79d1\u5b66\u5bb6\u4eec\u624b\u4e2d\u7684\u4e00\u628a\u5229\u5668\uff0c\u5e2e\u52a9\u4ed6\u4eec\u89e3\u5f00\u81ea\u7136\u754c\u7684\u5965\u79d8\uff0c\u5f00\u8f9f\u65b0\u7684\u9886\u57df\u3002<\/p>\n

\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c06\u6df1\u5165\u63a2\u8ba8\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u3001\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5728\u4e0d\u540c\u9886\u57df\u7684\u5177\u4f53\u5e94\u7528\uff0c\u4ee5\u671f\u5168\u9762\u4e86\u89e3\u8fd9\u4e00\u5316\u5b66\u754c\u7684\u91cd\u8981\u6210\u5458\u3002<\/p>\n

\n

\u7269\u7406\u5316\u5b66\u6027\u8d28\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u72ec\u7279\u9b45\u529b<\/h3>\n

\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u4f5c\u4e3a\u5316\u5b66\u754c\u7684\u660e\u661f\u5316\u5408\u7269\uff0c\u5176\u7269\u7406\u5316\u5b66\u6027\u8d28\u72b9\u5982\u4e00\u4ef6\u7cbe\u96d5\u7ec6\u7422\u7684\u827a\u672f\u54c1\uff0c\u6bcf\u4e00\u4e2a\u7ec6\u8282\u90fd\u5c55\u73b0\u7740\u975e\u51e1\u7684\u9b45\u529b\u3002\u4ece\u5206\u5b50\u7ed3\u6784\u5230\u6eb6\u89e3\u6027\uff0c\u518d\u5230\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e9b\u7279\u6027\u5171\u540c\u51b3\u5b9a\u4e86TMEDA\u5728\u5404\u79cd\u73af\u5883\u4e2d\u7684\u8868\u73b0\u548c\u7528\u9014\u3002<\/p>\n

\u5206\u5b50\u7ed3\u6784\u4e0e\u7a7a\u95f4\u6784\u578b<\/h4>\n

TMEDA\u7684\u5206\u5b50\u5f0f\u4e3aC6H16N2\uff0c\u5176\u5206\u5b50\u7ed3\u6784\u662f\u7531\u4e24\u4e2a\u6c2e\u539f\u5b50\u901a\u8fc7\u78b3\u94fe\u76f8\u8fde\uff0c\u5e76\u4e14\u6bcf\u4e2a\u6c2e\u539f\u5b50\u90fd\u88ab\u4e24\u4e2a\u7532\u57fa\uff08-CH3\uff09\u53d6\u4ee3\u3002\u8fd9\u79cd\u7279\u5b9a\u7684\u7ed3\u6784\u8d4b\u4e88\u4e86TMEDA\u4e00\u79cd\u72ec\u7279\u7684\u7a7a\u95f4\u6784\u578b\u2014\u2014\u7c7b\u4f3c\u4e8e\u4e00\u4e2a\u201c\u54d1\u94c3\u201d\u5f62\u72b6\uff0c\u4e24\u7aef\u662f\u5e26\u6709\u6b63\u7535\u6027\u7684\u6c2e\u539f\u5b50\uff0c\u4e2d\u95f4\u662f\u7531\u4e9a\u7532\u57fa\uff08-CH2-\uff09\u7ec4\u6210\u7684\u67d4\u6027\u8fde\u63a5\u6865\u3002\u6b63\u662f\u8fd9\u79cd\u7ed3\u6784\u4f7f\u5f97TMEDA\u80fd\u591f\u7075\u6d3b\u5730\u4e0e\u5176\u4ed6\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u87af\u5408\u7269\uff0c\u4ece\u800c\u5728\u50ac\u5316\u8fc7\u7a0b\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n\n\n\n\n\n\n\n
\u7279\u6027<\/strong><\/th>\n\u63cf\u8ff0<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC6H16N2<\/td>\n<\/tr>\n
\u7ed3\u6784\u7279\u70b9<\/td>\n\u53cc\u6c2e\u539f\u5b50\u914d\u4f53\uff0c\u4e24\u7aef\u5e26\u6b63\u7535\u8377\uff0c\u4e2d\u95f4\u4e3a\u67d4\u6027\u78b3\u94fe<\/td>\n<\/tr>\n
\u7a7a\u95f4\u6784\u578b<\/td>\n\u54d1\u94c3\u5f62\uff0c\u9002\u5408\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u5f62\u6210\u516d\u5143\u73af\u72b6\u87af\u5408\u7269<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6eb6\u89e3\u6027\u4e0e\u6781\u6027<\/h4>\n

TMEDA\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u8fd9\u4e3b\u8981\u5f97\u76ca\u4e8e\u5176\u5206\u5b50\u5185\u7684\u6c22\u952e\u4f5c\u7528\u4ee5\u53ca\u8f83\u5f3a\u7684\u6781\u6027\u3002\u5b83\u65e2\u80fd\u6eb6\u4e8e\u6c34\uff0c\u4e5f\u80fd\u5f88\u597d\u5730\u6eb6\u89e3\u4e8e\u5927\u591a\u6570\u6709\u673a\u6eb6\u5242\uff0c\u5982\u7532\u9187\u3001\u548c\u7b49\u3002\u8fd9\u79cd\u5e7f\u6cdb\u7684\u6eb6\u89e3\u80fd\u529b\u4f7fTMEDA\u5728\u5b9e\u9a8c\u64cd\u4f5c\u4e2d\u975e\u5e38\u65b9\u4fbf\uff0c\u65e0\u8bba\u662f\u5728\u6db2\u76f8\u53cd\u5e94\u8fd8\u662f\u56fa\u76f8\u5904\u7406\u4e2d\u90fd\u80fd\u8f7b\u677e\u5e94\u7528\u3002<\/p>\n\n\n\n\n\n\n\n
\u6eb6\u5242\u7c7b\u578b<\/strong><\/th>\n\u6eb6\u89e3\u60c5\u51b5<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u6c34<\/td>\n\u90e8\u5206\u6eb6\u89e3<\/td>\n<\/tr>\n
\u7532\u9187\/<\/td>\n\u5b8c\u5168\u6eb6\u89e3<\/td>\n<\/tr>\n
<\/td>\n\u6613\u6eb6<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6b64\u5916\uff0c\u7531\u4e8eTMEDA\u5206\u5b50\u4e2d\u542b\u6709\u591a\u4e2a\u4eb2\u6838\u6027\u6c2e\u539f\u5b50\uff0c\u56e0\u6b64\u5b83\u8868\u73b0\u51fa\u4e00\u5b9a\u7684\u78b1\u6027\u3002\u8fd9\u79cd\u78b1\u6027\u7279\u5f81\u4f7f\u5176\u80fd\u591f\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u7a33\u5b9a\u5b58\u5728\uff0c\u540c\u65f6\u8fd8\u80fd\u4e0e\u9178\u53cd\u5e94\u751f\u6210\u76f8\u5e94\u7684\u76d0\u7c7b\uff0c\u8fdb\u4e00\u6b65\u6269\u5c55\u4e86\u5176\u5e94\u7528\u8303\u56f4\u3002<\/p>\n

\u70ed\u7a33\u5b9a\u6027\u4e0e\u6325\u53d1\u6027<\/h4>\n

\u5c3d\u7ba1TMEDA\u7684\u5206\u5b50\u91cf\u8f83\u4f4e\uff08\u7ea6116 g\/mol\uff09\uff0c\u4f46\u5b83\u7684\u70ed\u7a33\u5b9a\u6027\u5374\u76f8\u5f53\u51fa\u8272\u3002\u5728\u5e38\u6e29\u4e0b\uff0cTMEDA\u5448\u73b0\u4e3a\u65e0\u8272\u900f\u660e\u6db2\u4f53\uff0c\u6cb8\u70b9\u7ea6\u4e3a105\u00b0C\uff0c\u8fd9\u610f\u5473\u7740\u5b83\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u4e0d\u4f1a\u8f7b\u6613\u5206\u89e3\uff0c\u800c\u662f\u4ee5\u84b8\u6c14\u5f62\u5f0f\u9038\u51fa\u3002\u8fd9\u79cd\u9002\u4e2d\u7684\u6325\u53d1\u6027\u4e0d\u4ec5\u4fdd\u8bc1\u4e86\u5176\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u8fd8\u4fbf\u4e8e\u901a\u8fc7\u84b8\u998f\u7b49\u624b\u6bb5\u8fdb\u884c\u7eaf\u5316\u3002<\/p>\n\n\n\n\n\n\n\n
\u6027\u8d28<\/strong><\/th>\n\u6570\u503c<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u6cb8\u70b9<\/td>\n105\u00b0C<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n-48\u00b0C<\/td>\n<\/tr>\n
\u84b8\u6c14\u538b<\/td>\n\u572820\u00b0C\u65f6\u7ea6\u4e3a1.3 kPa<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cTMEDA\u5728\u9ad8\u6e29\u4e0b\u53ef\u80fd\u4f1a\u53d1\u751f\u8131\u6c28\u53cd\u5e94\u6216\u5176\u4ed6\u526f\u53cd\u5e94\uff0c\u56e0\u6b64\u5728\u4f7f\u7528\u65f6\u9700\u8981\u7279\u522b\u6ce8\u610f\u6e29\u5ea6\u63a7\u5236\uff0c\u5c24\u5176\u662f\u5728\u6d89\u53ca\u654f\u611f\u53cd\u5e94\u7684\u60c5\u51b5\u4e0b\u3002<\/p>\n

\u5149\u8c31\u7279\u6027\u4e0e\u5206\u6790\u65b9\u6cd5<\/h4>\n

TMEDA\u7684\u5149\u8c31\u7279\u6027\u4e5f\u662f\u5176\u7814\u7a76\u4e2d\u7684\u4e00\u4e2a\u91cd\u8981\u65b9\u9762\u3002\u901a\u8fc7\u7ea2\u5916\u5149\u8c31\uff08IR\uff09\u3001\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u548c\u8d28\u8c31\uff08MS\uff09\u7b49\u73b0\u4ee3\u5206\u6790\u6280\u672f\uff0c\u53ef\u4ee5\u51c6\u786e\u5730\u8bc6\u522b\u548c\u8868\u5f81TMEDA\u7684\u5206\u5b50\u7ed3\u6784\u53ca\u5176\u53d8\u5316\u3002\u4f8b\u5982\uff0c\u57281H NMR\u8c31\u56fe\u4e2d\uff0cTMEDA\u7684\u7532\u57fa\u8d28\u5b50\u4fe1\u53f7\u901a\u5e38\u51fa\u73b0\u5728\u03b4 2.2 ppm\u5de6\u53f3\uff0c\u800c\u4e9a\u7532\u57fa\u8d28\u5b50\u5219\u4f4d\u4e8e\u03b4 3.1 ppm\u9644\u8fd1\u3002\u8fd9\u4e9b\u7279\u5f81\u5cf0\u4e3a\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7684\u53c2\u8003\u4fe1\u606f\u3002<\/p>\n\n\n\n\n\n\n\n
\u5206\u6790\u65b9\u6cd5<\/strong><\/th>\n\u5173\u952e\u53c2\u6570<\/strong><\/th>\n<\/tr>\n<\/thead>\n
IR\u5149\u8c31<\/td>\n\u5728~3300 cm\u207b\u00b9\u5904\u51fa\u73b0\u660e\u663e\u7684N-H\u4f38\u7f29\u632f\u52a8\u5438\u6536\u5cf0<\/td>\n<\/tr>\n
1H NMR<\/td>\n\u7532\u57fa\u8d28\u5b50\uff1a\u03b4 2.2 ppm\uff1b\u4e9a\u7532\u57fa\u8d28\u5b50\uff1a\u03b4 3.1 ppm<\/td>\n<\/tr>\n
MS\u8d28\u8c31<\/td>\n\u5206\u5b50\u79bb\u5b50\u5cf0[M+H]\u207a = 117<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u51ed\u501f\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u3001\u826f\u597d\u7684\u6eb6\u89e3\u6027\u3001\u7a33\u5b9a\u7684\u70ed\u6027\u80fd\u4ee5\u53ca\u660e\u786e\u7684\u5149\u8c31\u7279\u6027\uff0c\u5728\u5316\u5b66\u9886\u57df\u4e2d\u5360\u636e\u4e86\u91cd\u8981\u5730\u4f4d\u3002\u8fd9\u4e9b\u6027\u8d28\u4e0d\u4ec5\u4e3a\u5176\u591a\u6837\u5316\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\uff0c\u4e5f\u4e3a\u79d1\u5b66\u5bb6\u4eec\u7684\u7814\u7a76\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e30\u5bcc\u7684\u7d20\u6750\u548c\u7075\u611f\u3002<\/p>\n

\n

\u5408\u6210\u8def\u5f84\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u8bde\u751f\u4e4b\u65c5<\/h3>\n

\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u7684\u5236\u5907\u8fc7\u7a0b\u72b9\u5982\u4e00\u573a\u7cbe\u5fc3\u7b56\u5212\u7684\u5316\u5b66\u4ea4\u54cd\u4e50\uff0c\u6bcf\u4e00\u6b65\u90fd\u9700\u8981\u7cbe\u786e\u7684\u64cd\u4f5c\u548c\u4e25\u8c28\u7684\u6761\u4ef6\u63a7\u5236\u3002\u6839\u636e\u6587\u732e\u8bb0\u8f7d\u548c\u5b9e\u9a8c\u7ecf\u9a8c\uff0c\u76ee\u524d\u4e3b\u6d41\u7684\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u76f4\u63a5\u5408\u6210\u6cd5\u548c\u95f4\u63a5\u5408\u6210\u6cd5\u4e24\u5927\u7c7b\u3002\u4e0b\u9762\u6211\u4eec\u5c06\u8be6\u7ec6\u4ecb\u7ecd\u8fd9\u4e24\u79cd\u65b9\u6cd5\u7684\u5177\u4f53\u6b65\u9aa4\u53ca\u4f18\u7f3a\u70b9\u3002<\/p>\n

\u76f4\u63a5\u5408\u6210\u6cd5\uff1a\u7b80\u6d01\u9ad8\u6548\u7684\u8def\u7ebf<\/h4>\n

\u76f4\u63a5\u5408\u6210\u6cd5\u662f\u5e38\u89c1\u7684\u5236\u5907TMEDA\u7684\u65b9\u5f0f\u4e4b\u4e00\uff0c\u5176\u6838\u5fc3\u601d\u60f3\u662f\u901a\u8fc7\u7b80\u5355\u7684\u5316\u5b66\u53cd\u5e94\u4e00\u6b65\u5230\u4f4d\u5730\u83b7\u5f97\u76ee\u6807\u4ea7\u7269\u3002\u8be5\u65b9\u6cd5\u901a\u5e38\u4ee5\u4e59\u4e8c\u80fa\uff08H\u2082NCH\u2082CH\u2082NH\u2082\uff09\u4e3a\u539f\u6599\uff0c\u5229\u7528\u7532\u57fa\u5316\u8bd5\u5242\uff08\u5982\u786b\u9178\u4e8c\u7532\u916f\u6216\u7898\u7532\u70f7\uff09\u5bf9\u5176\u8fdb\u884c\u53cc\u7532\u57fa\u5316\u5904\u7406\uff0c\u4ece\u800c\u5f15\u5165\u56db\u4e2a\u7532\u57fa\u57fa\u56e2\u3002<\/p>\n

\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/h5>\n

[
\nH_2NCH_2CH_2NH_2 + 4 CH_3I xrightarrow{KOH} (CH_3)_2NCH_2CH_2N(CH_3)_2 + 4 HI
\n]<\/p>\n

\u5728\u5b9e\u9645\u64cd\u4f5c\u4e2d\uff0c\u4e3a\u4e86\u63d0\u9ad8\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u6536\u7387\uff0c\u901a\u5e38\u4f1a\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\u6b64\u53cd\u5e94\u3002\u5e38\u7528\u7684\u78b1\u5305\u62ec\u6c22\u6c27\u5316\u94be\uff08KOH\uff09\u6216\u78b3\u9178\u94be\uff08K\u2082CO\u2083\uff09\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u9632\u6b62\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e00\u822c\u63a7\u5236\u5728\u5ba4\u6e29\u81f350\u00b0C\u4e4b\u95f4\u3002<\/p>\n\n\n\n\n\n\n\n
\u6b65\u9aa4<\/strong><\/th>\n\u6761\u4ef6<\/strong><\/th>\n\u4f18\u70b9<\/strong><\/th>\n\u7f3a\u70b9<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u6dfb\u52a0\u7532\u57fa\u5316\u8bd5\u5242<\/td>\n\u6e29\u5ea6\uff1a20-50\u00b0C\uff1b\u6405\u62cc\uff1a\u6301\u7eed<\/td>\n\u64cd\u4f5c\u7b80\u5355\uff0c\u6613\u4e8e\u63a7\u5236<\/td>\n\u4f7f\u7528\u6709\u6bd2\u8bd5\u5242\uff0c\u9700\u6ce8\u610f\u5b89\u5168\u9632\u62a4<\/td>\n<\/tr>\n
\u4e2d\u548c\u591a\u4f59\u78b1<\/td>\n\u52a0\u5165\u7a00\u9178\u8c03\u8282pH\u503c<\/td>\n\u6536\u7387\u8f83\u9ad8\uff0c\u53ef\u8fbe90%\u4ee5\u4e0a<\/td>\n\u53ef\u80fd\u4ea7\u751f\u5c11\u91cf\u6742\u8d28\uff0c\u9700\u8fdb\u4e00\u6b65\u7eaf\u5316<\/td>\n<\/tr>\n
\u63d0\u7eaf\u7ec8\u4ea7\u7269<\/td>\n\u51cf\u538b\u84b8\u998f\u6216\u91cd\u7ed3\u6676<\/td>\n\u7eaf\u5ea6\u9ad8\uff0c\u6ee1\u8db3\u5de5\u4e1a\u9700\u6c42<\/td>\n\u8bbe\u5907\u8981\u6c42\u8f83\u9ad8\uff0c\u6210\u672c\u76f8\u5bf9\u589e\u52a0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u95f4\u63a5\u5408\u6210\u6cd5\uff1a\u591a\u6b65\u4f18\u5316\u7b56\u7565<\/h4>\n

\u5bf9\u4e8e\u67d0\u4e9b\u7279\u6b8a\u5e94\u7528\u573a\u666f\uff0c\u53ef\u80fd\u9700\u8981\u66f4\u9ad8\u7eaf\u5ea6\u6216\u66f4\u5927\u89c4\u6a21\u7684TMEDA\u751f\u4ea7\u3002\u6b64\u65f6\uff0c\u95f4\u63a5\u5408\u6210\u6cd5\u4fbf\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u8fd9\u79cd\u65b9\u6cd5\u901a\u8fc7\u591a\u6b65\u53cd\u5e94\u9010\u6b65\u6784\u5efa\u76ee\u6807\u5206\u5b50\uff0c\u867d\u7136\u6d41\u7a0b\u8f83\u4e3a\u590d\u6742\uff0c\u4f46\u53ef\u4ee5\u663e\u8457\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\uff0c\u63d0\u5347\u4ea7\u54c1\u54c1\u8d28\u3002<\/p>\n

\u6b65\u901a\u5e38\u662f\u5236\u5907\u5355\u7532\u57fa\u5316\u7684\u4e2d\u95f4\u4f53\uff0c\u4f8b\u5982N,N-\u4e8c\u7532\u57fa\u4e59\u4e8c\u80fa\uff08DMEDA\uff09\u3002\u968f\u540e\uff0c\u518d\u5bf9\u8be5\u4e2d\u95f4\u4f53\u8fdb\u884c\u7b2c\u4e8c\u6b21\u7532\u57fa\u5316\u53cd\u5e94\uff0c\u7ec8\u5f97\u5230\u5b8c\u5168\u5bf9\u79f0\u7684TMEDA\u3002<\/p>\n

\u6b65\uff1a\u5355\u7532\u57fa\u5316\u53cd\u5e94<\/h5>\n

[
\nH_2NCH_2CH_2NH_2 + 2 CH_3I xrightarrow{NaHCO_3} H_2NCH_2CH_2N(CH_3)_2 + 2 HI
\n]<\/p>\n

\u7b2c\u4e8c\u6b65\uff1a\u4e8c\u6b21\u7532\u57fa\u5316\u53cd\u5e94<\/h5>\n

[
\nH_2NCH_2CH_2N(CH_3)_2 + 2 CH_3I xrightarrow{K\u2082CO\u2083} (CH_3)_2NCH_2CH_2N(CH_3)_2 + 2 HI
\n]<\/p>\n

\u4e0e\u76f4\u63a5\u5408\u6210\u6cd5\u76f8\u6bd4\uff0c\u95f4\u63a5\u5408\u6210\u6cd5\u7684\u4f18\u52bf\u5728\u4e8e\u53cd\u5e94\u6761\u4ef6\u66f4\u4e3a\u6e29\u548c\uff0c\u526f\u53cd\u5e94\u8f83\u5c11\uff0c\u9002\u5408\u5927\u89c4\u6a21\u5de5\u4e1a\u5316\u751f\u4ea7\u3002\u7136\u800c\uff0c\u8fd9\u4e5f\u610f\u5473\u7740\u6574\u4e2a\u8fc7\u7a0b\u66f4\u52a0\u8017\u65f6\u4e14\u6210\u672c\u7565\u9ad8\u3002<\/p>\n\n\n\n\n\n\n\n
\u6b65\u9aa4<\/strong><\/th>\n\u6761\u4ef6<\/strong><\/th>\n\u4f18\u70b9<\/strong><\/th>\n\u7f3a\u70b9<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u5355\u7532\u57fa\u5316\u53cd\u5e94<\/td>\n\u6e29\u5ea6\uff1a10-30\u00b0C\uff1bpH\u7f13\u51b2\u6eb6\u6db2<\/td>\n\u6761\u4ef6\u6e29\u548c\uff0c\u9009\u62e9\u6027\u597d<\/td>\n\u9700\u8981\u989d\u5916\u5206\u79bb\u4e2d\u95f4\u4f53<\/td>\n<\/tr>\n
\u4e8c\u6b21\u7532\u57fa\u5316\u53cd\u5e94<\/td>\n\u6e29\u5ea6\uff1a30-50\u00b0C\uff1b\u5f3a\u78b1\u50ac\u5316<\/td>\n\u4ea7\u54c1\u7eaf\u5ea6\u9ad8\uff0c\u9002\u7528\u4e8e\u9ad8\u7aef\u5e94\u7528<\/td>\n\u6d41\u7a0b\u8f83\u957f\uff0c\u8bbe\u5907\u6295\u8d44\u8f83\u5927<\/td>\n<\/tr>\n
\u7ec8\u63d0\u7eaf<\/td>\n\u84b8\u998f\u6216\u67f1\u5c42\u6790<\/td>\n\u7b26\u5408\u836f\u7528\u7ea7\u6807\u51c6<\/td>\n\u603b\u4f53\u6210\u672c\u8f83\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u65b0\u5174\u5408\u6210\u6280\u672f\uff1a\u7eff\u8272\u5316\u5b66\u7684\u5c1d\u8bd5<\/h4>\n

\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u73af\u4fdd\u610f\u8bc6\u7684\u589e\u5f3a\uff0c\u79d1\u5b66\u5bb6\u4eec\u4e5f\u5f00\u59cb\u63a2\u7d22\u66f4\u52a0\u73af\u4fdd\u7684TMEDA\u5408\u6210\u65b9\u6cd5\u3002\u4f8b\u5982\uff0c\u91c7\u7528\u751f\u7269\u50ac\u5316\u5242\u4ee3\u66ff\u4f20\u7edf\u5316\u5b66\u8bd5\u5242\uff0c\u6216\u8005\u5229\u7528\u5fae\u6ce2\u8f85\u52a9\u6280\u672f\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\u3002\u8fd9\u4e9b\u65b0\u6280\u672f\u4e0d\u4ec5\u51cf\u5c11\u4e86\u6709\u5bb3\u5e9f\u5f03\u7269\u7684\u6392\u653e\uff0c\u8fd8\u5927\u5e45\u63d0\u9ad8\u4e86\u53cd\u5e94\u6548\u7387\u3002<\/p>\n\n\n\n\n\n\n
\u6280\u672f\u540d\u79f0<\/strong><\/th>\n\u7279\u70b9<\/strong><\/th>\n\u6f5c\u5728\u4f18\u52bf<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u751f\u7269\u50ac\u5316<\/td>\n\u4f7f\u7528\u9176\u4fc3\u53cd\u5e94\u66ff\u4ee3\u5316\u5b66\u8bd5\u5242<\/td>\n\u66f4\u52a0\u73af\u4fdd\uff0c\u51cf\u5c11\u6c61\u67d3<\/td>\n<\/tr>\n
\u5fae\u6ce2\u8f85\u52a9<\/td>\n\u5229\u7528\u9ad8\u9891\u7535\u78c1\u6ce2\u4fc3\u8fdb\u5206\u5b50\u95f4\u78b0\u649e<\/td>\n\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4\uff0c\u964d\u4f4e\u80fd\u8017<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u603b\u4e4b\uff0c\u65e0\u8bba\u91c7\u7528\u54ea\u79cd\u5408\u6210\u65b9\u6cd5\uff0cTMEDA\u7684\u5236\u5907\u90fd\u79bb\u4e0d\u5f00\u7cbe\u786e\u7684\u5de5\u827a\u63a7\u5236\u548c\u79d1\u5b66\u7684\u8bbe\u8ba1\u601d\u8def\u3002\u672a\u6765\uff0c\u968f\u7740\u79d1\u6280\u7684\u8fdb\u6b65\uff0c\u76f8\u4fe1\u4f1a\u6709\u66f4\u591a\u9ad8\u6548\u3001\u7ecf\u6d4e\u4e14\u73af\u4fdd\u7684\u5408\u6210\u65b9\u6848\u4e0d\u65ad\u6d8c\u73b0\u3002<\/p>\n

\n

\u5de5\u4e1a\u4e0e\u79d1\u7814\u4e2d\u7684\u5e7f\u6cdb\u5e94\u7528\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u89d2\u8272\u62c5\u5f53<\/h3>\n

\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u5316\u5408\u7269\uff0c\u5728\u5de5\u4e1a\u751f\u4ea7\u548c\u79d1\u5b66\u7814\u7a76\u9886\u57df\u5c55\u73b0\u51fa\u4e86\u6781\u5927\u7684\u4ef7\u503c\u3002\u5b83\u4e0d\u4ec5\u662f\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u5242\u548c\u914d\u4f53\uff0c\u8fd8\u5728\u6750\u6599\u79d1\u5b66\u3001\u533b\u836f\u7814\u53d1\u7b49\u591a\u4e2a\u65b9\u9762\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u7684\u89d2\u8272<\/h4>\n

\u5728\u5de5\u4e1a\u9886\u57df\uff0cTMEDA\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50ac\u5316\u5242\u4f53\u7cfb\u4e2d\uff0c\u7279\u522b\u662f\u5728\u805a\u5408\u53cd\u5e94\u548c\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u4e2d\u3002\u5b83\u80fd\u6709\u6548\u5730\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u6539\u5584\u4ea7\u54c1\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u5728\u805a\u6c28\u916f\u6ce1\u6cab\u5851\u6599\u7684\u751f\u4ea7\u8fc7\u7a0b\u4e2d\uff0cTMEDA\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u8c03\u63a7\u53d1\u6ce1\u901f\u5ea6\u548c\u6ce1\u6cab\u7ed3\u6784\uff0c\u4ece\u800c\u5f71\u54cd\u7ec8\u4ea7\u54c1\u7684\u5bc6\u5ea6\u548c\u786c\u5ea6\u3002\u6b64\u5916\uff0c\u5728\u5c3c\u9f99\u7ea4\u7ef4\u7684\u5236\u9020\u4e2d\uff0cTMEDA\u540c\u6837\u8d77\u5230\u4e86\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\uff0c\u5b83\u6709\u52a9\u4e8e\u63d0\u5347\u7ea4\u7ef4\u7684\u5f3a\u5ea6\u548c\u8010\u78e8\u6027\u3002<\/p>\n\n\n\n\n\n\n
\u5de5\u4e1a\u5e94\u7528<\/strong><\/th>\n\u529f\u80fd<\/strong><\/th>\n\u6548\u679c<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u805a\u6c28\u916f\u6ce1\u6cab\u751f\u4ea7<\/td>\n\u63a7\u5236\u53d1\u6ce1\u901f\u7387\u548c\u7ed3\u6784<\/td>\n\u6539\u5584\u6ce1\u6cab\u5747\u5300\u5ea6\u548c\u673a\u68b0\u6027\u80fd<\/td>\n<\/tr>\n
\u5c3c\u9f99\u7ea4\u7ef4\u5236\u9020<\/td>\n\u63d0\u5347\u7ea4\u7ef4\u5f3a\u5ea6\u548c\u8010\u78e8\u6027<\/td>\n\u589e\u5f3a\u7eba\u7ec7\u54c1\u8d28\u91cf<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u5728\u79d1\u5b66\u7814\u7a76\u4e2d\u7684\u8d21\u732e<\/h4>\n

\u8fdb\u5165\u5b9e\u9a8c\u5ba4\uff0cTMEDA\u66f4\u662f\u5c55\u73b0\u4e86\u5176\u5353\u8d8a\u7684\u79d1\u5b66\u4ef7\u503c\u3002\u4f5c\u4e3a\u914d\u4f53\uff0c\u5b83\u80fd\u591f\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u87af\u5408\u7269\uff0c\u8fd9\u5bf9\u4e8e\u7814\u7a76\u91d1\u5c5e\u914d\u5408\u7269\u7684\u7ed3\u6784\u548c\u6027\u8d28\u81f3\u5173\u91cd\u8981\u3002\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0cTMEDA\u7ecf\u5e38\u88ab\u7528\u4f5cLewis\u78b1\uff0c\u53c2\u4e0e\u5404\u79cd\u52a0\u6210\u3001\u6d88\u9664\u53cd\u5e94\uff0c\u6781\u5927\u5730\u4e30\u5bcc\u4e86\u6709\u673a\u5316\u5b66\u7684\u53cd\u5e94\u7c7b\u578b\u3002<\/p>\n\n\n\n\n\n\n
\u79d1\u7814\u5e94\u7528<\/strong><\/th>\n\u529f\u80fd<\/strong><\/th>\n\u610f\u4e49<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u91d1\u5c5e\u914d\u5408\u7269\u7814\u7a76<\/td>\n\u5f62\u6210\u7a33\u5b9a\u87af\u5408\u7269<\/td>\n\u63ed\u793a\u91d1\u5c5e\u79bb\u5b50\u884c\u4e3a<\/td>\n<\/tr>\n
\u6709\u673a\u5408\u6210<\/td>\n\u53c2\u4e0e\u591a\u79cd\u53cd\u5e94<\/td>\n\u6269\u5c55\u53cd\u5e94\u9014\u5f84<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u5728\u533b\u836f\u5f00\u53d1\u4e2d\u7684\u6f5c\u529b<\/h4>\n

\u5728\u533b\u836f\u9886\u57df\uff0cTMEDA\u7684\u7528\u9014\u4e5f\u4e0d\u5bb9\u5ffd\u89c6\u3002\u5b83\u88ab\u7528\u4e8e\u836f\u7269\u5408\u6210\u4e2d\uff0c\u5e2e\u52a9\u6784\u5efa\u590d\u6742\u7684\u5206\u5b50\u9aa8\u67b6\u3002\u6b64\u5916\uff0cTMEDA\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u836f\u7269\u8f7d\u4f53\u7684\u4e00\u90e8\u5206\uff0c\u63d0\u9ad8\u836f\u7269\u7684\u9776\u5411\u6027\u548c\u7597\u6548\u3002\u4f8b\u5982\uff0c\u5728\u6297\u764c\u836f\u7269\u7684\u7814\u7a76\u4e2d\uff0cTMEDA\u7684\u5f15\u5165\u53ef\u4ee5\u4f7f\u836f\u7269\u66f4\u597d\u5730\u8bc6\u522b\u5e76\u653b\u51fb\u764c\u7ec6\u80de\uff0c\u540c\u65f6\u51cf\u5c11\u5bf9\u6b63\u5e38\u7ec6\u80de\u7684\u4f24\u5bb3\u3002<\/p>\n

\u5bf9\u73af\u5883\u4fdd\u62a4\u7684\u5f71\u54cd<\/h4>\n

\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u968f\u7740\u73af\u4fdd\u610f\u8bc6\u7684\u589e\u5f3a\uff0cTMEDA\u5728\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u5e94\u7528\u4e5f\u65e5\u76ca\u53d7\u5230\u5173\u6ce8\u3002\u901a\u8fc7\u6539\u8fdb\u751f\u4ea7\u5de5\u827a\uff0c\u51cf\u5c11\u526f\u4ea7\u7269\u548c\u5e9f\u5f03\u7269\u7684\u4ea7\u751f\uff0cTMEDA\u6b63\u5728\u671d\u7740\u66f4\u52a0\u73af\u4fdd\u7684\u65b9\u5411\u53d1\u5c55\u3002\u8fd9\u4e0d\u4ec5\u7b26\u5408\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u7406\u5ff5\uff0c\u4e5f\u4e3a\u672a\u6765\u7684\u5316\u5de5\u4ea7\u4e1a\u6307\u660e\u4e86\u65b0\u7684\u65b9\u5411\u3002<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u5de5\u4e1a\u751f\u4ea7\u548c\u79d1\u5b66\u7814\u7a76\u4e2d\u626e\u6f14\u7740\u591a\u91cd\u89d2\u8272\uff0c\u5176\u591a\u6837\u5316\u7684\u5e94\u7528\u524d\u666f\u4ee4\u4eba\u671f\u5f85\u3002\u968f\u7740\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u76f8\u4fe1TMEDA\u5c06\u5728\u66f4\u591a\u7684\u9886\u57df\u5c55\u73b0\u51fa\u5176\u72ec\u7279\u7684\u9b45\u529b\u548c\u4ef7\u503c\u3002<\/p>\n

\n

\u5b89\u5168\u4e0e\u6cd5\u89c4\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u4f7f\u7528\u89c4\u8303\u4e0e\u7ba1\u7406<\/h3>\n

\u5728\u4eab\u53d7\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u5e26\u6765\u7684\u4fbf\u5229\u4e0e\u6548\u76ca\u7684\u540c\u65f6\uff0c\u6211\u4eec\u5fc5\u987b\u6b63\u89c6\u5176\u6f5c\u5728\u7684\u5b89\u5168\u98ce\u9669\u548c\u4e25\u683c\u7684\u6cd5\u89c4\u8981\u6c42\u3002\u5408\u7406\u4f7f\u7528TMEDA\u4e0d\u4ec5\u80fd\u786e\u4fdd\u64cd\u4f5c\u4eba\u5458\u7684\u5b89\u5168\uff0c\u8fd8\u80fd\u7ef4\u62a4\u73af\u5883\u7684\u5065\u5eb7\uff0c\u907f\u514d\u4e0d\u5fc5\u8981\u7684\u635f\u5bb3\u3002<\/p>\n

\u5065\u5eb7\u4e0e\u5b89\u5168\u8003\u91cf<\/h4>\n

\u9996\u5148\uff0cTMEDA\u4f5c\u4e3a\u4e00\u79cd\u5316\u5b66\u54c1\uff0c\u5176\u6bd2\u6027\u867d\u4e0d\u9ad8\uff0c\u4f46\u4ecd\u9700\u8c28\u614e\u5bf9\u5f85\u3002\u957f\u671f\u66b4\u9732\u4e8e\u9ad8\u6d53\u5ea6\u7684TMEDA\u73af\u5883\u4e2d\u53ef\u80fd\u5bfc\u81f4\u547c\u5438\u9053\u523a\u6fc0\u3001\u76ae\u80a4\u8fc7\u654f\u751a\u81f3\u795e\u7ecf\u7cfb\u7edf\u7d0a\u4e71\u3002\u56e0\u6b64\uff0c\u6240\u6709\u63a5\u89e6TMEDA\u7684\u64cd\u4f5c\u5747\u5e94\u5728\u901a\u98ce\u826f\u597d\u7684\u73af\u5883\u4e0b\u8fdb\u884c\uff0c\u5e76\u4f69\u6234\u9002\u5f53\u7684\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\uff0c\u5982\u624b\u5957\u3001\u62a4\u76ee\u955c\u548c\u9632\u6bd2\u9762\u5177\u3002<\/p>\n\n\n\n\n\n\n\n
\u5371\u5bb3\u7c7b\u522b<\/strong><\/th>\n\u9884\u9632\u63aa\u65bd<\/strong><\/th>\n\u7d27\u6025\u5904\u7406<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u547c\u5438\u9053\u523a\u6fc0<\/td>\n\u4f7f\u7528\u5c40\u90e8\u6392\u6c14\u7cfb\u7edf<\/td>\n\u82e5\u5438\u5165\uff0c\u7acb\u5373\u79fb\u81f3\u65b0\u9c9c\u7a7a\u6c14\u5904<\/td>\n<\/tr>\n
\u76ae\u80a4\u63a5\u89e6<\/td>\n\u7a7f\u6234\u8010\u5316\u5b66\u54c1\u624b\u5957<\/td>\n\u7528\u5927\u91cf\u6e05\u6c34\u51b2\u6d17\u53d7\u5f71\u54cd\u533a\u57df<\/td>\n<\/tr>\n
\u773c\u775b\u63a5\u89e6<\/td>\n\u6234\u62a4\u76ee\u955c<\/td>\n\u7528\u6c34\u51b2\u6d17\u81f3\u5c1115\u5206\u949f<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6b64\u5916\uff0cTMEDA\u5177\u6709\u4e00\u5b9a\u7684\u53ef\u71c3\u6027\uff0c\u50a8\u5b58\u65f6\u5e94\u8fdc\u79bb\u706b\u6e90\u548c\u9ad8\u6e29\u73af\u5883\uff0c\u4ee5\u9632\u706b\u707e\u4e8b\u6545\u7684\u53d1\u751f\u3002\u4efb\u4f55\u6cc4\u6f0f\u90fd\u5e94\u53ca\u65f6\u6e05\u7406\uff0c\u907f\u514d\u6269\u6563\u9020\u6210\u66f4\u5927\u7684\u73af\u5883\u6c61\u67d3\u3002<\/p>\n

\u6cd5\u89c4\u4e0e\u6807\u51c6<\/h4>\n

\u5404\u56fd\u653f\u5e9c\u548c\u56fd\u9645\u7ec4\u7ec7\u9488\u5bf9\u5316\u5b66\u54c1\u7684\u5b89\u5168\u7ba1\u7406\u548c\u4f7f\u7528\u5236\u5b9a\u4e86\u4e00\u7cfb\u5217\u6cd5\u89c4\u548c\u6807\u51c6\uff0c\u65e8\u5728\u89c4\u8303\u5316\u5b66\u54c1\u7684\u751f\u4ea7\u3001\u8fd0\u8f93\u3001\u50a8\u5b58\u548c\u4f7f\u7528\u3002\u4f8b\u5982\uff0c\u6b27\u76df\u7684REACH\u6cd5\u89c4\u8981\u6c42\u4f01\u4e1a\u5bf9\u5176\u751f\u4ea7\u7684\u5316\u5b66\u54c1\u8fdb\u884c\u5168\u9762\u7684\u98ce\u9669\u8bc4\u4f30\uff0c\u5e76\u63d0\u4ea4\u76f8\u5173\u6570\u636e\u4ee5\u4f9b\u5ba1\u6838\u3002\u5728\u7f8e\u56fd\uff0cEPA\uff08\u73af\u5883\u4fdd\u62a4\u7f72\uff09\u5219\u8d1f\u8d23\u76d1\u7763\u5316\u5b66\u54c1\u7684\u5b89\u5168\u6027\uff0c\u786e\u4fdd\u5176\u4e0d\u4f1a\u5bf9\u516c\u4f17\u5065\u5eb7\u548c\u73af\u5883\u6784\u6210\u5a01\u80c1\u3002<\/p>\n\n\n\n\n\n\n
\u6cd5\u89c4\u540d\u79f0<\/strong><\/th>\n\u4e3b\u8981\u5185\u5bb9<\/strong><\/th>\n\u9002\u7528\u8303\u56f4<\/strong><\/th>\n<\/tr>\n<\/thead>\n
REACH\u6cd5\u89c4<\/td>\n\u5316\u5b66\u54c1\u6ce8\u518c\u3001\u8bc4\u4f30\u3001\u6388\u6743\u548c\u9650\u5236<\/td>\n\u6b27\u76df\u6210\u5458\u56fd<\/td>\n<\/tr>\n
EPA\u89c4\u5b9a<\/td>\n\u5316\u5b66\u54c1\u5b89\u5168\u6027\u8bc4\u4f30\u548c\u7ba1\u7406<\/td>\n\u7f8e\u56fd<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u5728\u4e2d\u56fd\uff0cGB\/T 16483-2008\u300a\u5316\u5b66\u54c1\u5b89\u5168\u6280\u672f\u8bf4\u660e\u4e66\u7f16\u5199\u89c4\u5b9a\u300b\u8be6\u7ec6\u8bf4\u660e\u4e86\u5316\u5b66\u54c1\u5b89\u5168\u6280\u672f\u8bf4\u660e\u4e66\u7684\u5185\u5bb9\u548c\u683c\u5f0f\uff0c\u786e\u4fdd\u4f7f\u7528\u8005\u80fd\u591f\u5145\u5206\u4e86\u89e3\u5316\u5b66\u54c1\u7684\u5371\u9669\u7279\u6027\u548c\u9632\u62a4\u63aa\u65bd\u3002\u540c\u65f6\uff0c\u300a\u5371\u9669\u5316\u5b66\u54c1\u5b89\u5168\u7ba1\u7406\u6761\u4f8b\u300b\u660e\u786e\u4e86\u5316\u5b66\u54c1\u5728\u5404\u4e2a\u73af\u8282\u7684\u5b89\u5168\u7ba1\u7406\u8981\u6c42\uff0c\u5f3a\u5316\u4e86\u4f01\u4e1a\u7684\u4e3b\u4f53\u8d23\u4efb\u3002<\/p>\n

\u73af\u5883\u4fdd\u62a4<\/h4>\n

\u9664\u4e86\u4eba\u8eab\u5b89\u5168\u548c\u5408\u89c4\u6027\u5916\uff0c\u73af\u5883\u4fdd\u62a4\u4e5f\u662f\u4f7f\u7528TMEDA\u65f6\u4e0d\u53ef\u5ffd\u89c6\u7684\u4e00\u4e2a\u65b9\u9762\u3002\u4e0d\u5f53\u5904\u7f6eTMEDA\u53ef\u80fd\u5bfc\u81f4\u571f\u58e4\u548c\u6c34\u4f53\u6c61\u67d3\uff0c\u8fdb\u800c\u5f71\u54cd\u751f\u6001\u7cfb\u7edf\u5e73\u8861\u3002\u56e0\u6b64\uff0c\u4f01\u4e1a\u5728\u4f7f\u7528TMEDA\u65f6\u5e94\u91c7\u53d6\u6709\u6548\u63aa\u65bd\u51cf\u5c11\u6392\u653e\uff0c\u4f8b\u5982\u901a\u8fc7\u56de\u6536\u518d\u5229\u7528\u51cf\u5c11\u6d6a\u8d39\uff0c\u6216\u8005\u91c7\u7528\u5148\u8fdb\u7684\u5e9f\u6c34\u5904\u7406\u6280\u672f\u51c0\u5316\u6392\u653e\u7269\u3002<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5b89\u5168\u4e0e\u6cd5\u89c4\u662f\u4f7f\u7528\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u8fc7\u7a0b\u4e2d\u5fc5\u987b\u91cd\u89c6\u7684\u4e24\u4e2a\u65b9\u9762\u3002\u53ea\u6709\u4e25\u683c\u9075\u5b88\u76f8\u5173\u89c4\u5b9a\uff0c\u91c7\u53d6\u9002\u5f53\u7684\u5b89\u5168\u63aa\u65bd\uff0c\u624d\u80fd\u5927\u9650\u5ea6\u5730\u53d1\u6325TMEDA\u7684\u4ef7\u503c\uff0c\u540c\u65f6\u4fdd\u969c\u4eba\u7c7b\u5065\u5eb7\u548c\u751f\u6001\u73af\u5883\u7684\u5b89\u5168\u3002<\/p>\n

\n

\u5c55\u671b\u672a\u6765\uff1a\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u7684\u53d1\u5c55\u524d\u666f\u4e0e\u65b0\u5174\u8d8b\u52bf<\/h3>\n

\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u98de\u901f\u53d1\u5c55\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\uff08TMEDA\uff09\u7684\u5e94\u7528\u9886\u57df\u6b63\u5728\u4e0d\u65ad\u62d3\u5c55\uff0c\u5176\u672a\u6765\u53d1\u5c55\u524d\u666f\u5c24\u4e3a\u5e7f\u9614\u3002\u65e0\u8bba\u662f\u65b0\u6750\u6599\u7684\u5f00\u53d1\uff0c\u8fd8\u662f\u7eff\u8272\u5316\u5b66\u7684\u5b9e\u8df5\uff0cTMEDA\u90fd\u5728\u5176\u4e2d\u626e\u6f14\u7740\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n

\u65b0\u6750\u6599\u9886\u57df\u7684\u7a81\u7834<\/h4>\n

\u5728\u6750\u6599\u79d1\u5b66\u4e2d\uff0cTMEDA\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u9ad8\u6027\u80fd\u805a\u5408\u7269\u548c\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u3002\u901a\u8fc7\u8c03\u6574TMEDA\u7684\u6bd4\u4f8b\u548c\u53cd\u5e94\u6761\u4ef6\uff0c\u79d1\u5b66\u5bb6\u4eec\u80fd\u591f\u5408\u6210\u51fa\u5177\u6709\u7279\u5b9a\u7269\u7406\u5316\u5b66\u6027\u8d28\u7684\u65b0\u6750\u6599\u3002\u4f8b\u5982\uff0c\u6dfb\u52a0TMEDA\u7684\u73af\u6c27\u6811\u8102\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u97e7\u6027\u548c\u6297\u51b2\u51fb\u6027\uff0c\u975e\u5e38\u9002\u5408\u822a\u7a7a\u822a\u5929\u548c\u6c7d\u8f66\u5de5\u4e1a\u7684\u9700\u6c42\u3002\u6b64\u5916\uff0cTMEDA\u8fd8\u88ab\u7528\u6765\u6539\u826f\u5bfc\u7535\u805a\u5408\u7269\uff0c\u63d0\u9ad8\u5176\u5bfc\u7535\u6548\u7387\u548c\u7a33\u5b9a\u6027\uff0c\u8fd9\u5bf9\u4e8e\u7535\u5b50\u5668\u4ef6\u7684\u5c0f\u578b\u5316\u548c\u667a\u80fd\u5316\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n\n\n\n\n\n\n
\u65b0\u6750\u6599<\/strong><\/th>\n\u6539\u8fdb\u7279\u6027<\/strong><\/th>\n\u5e94\u7528\u9886\u57df<\/strong><\/th>\n<\/tr>\n<\/thead>\n
\u73af\u6c27\u6811\u8102<\/td>\n\u63d0\u9ad8\u97e7\u6027\u548c\u6297\u51b2\u51fb\u6027<\/td>\n\u822a\u7a7a\u822a\u5929\u3001\u6c7d\u8f66\u5236\u9020<\/td>\n<\/tr>\n
\u5bfc\u7535\u805a\u5408\u7269<\/td>\n\u589e\u5f3a\u5bfc\u7535\u6548\u7387\u548c\u7a33\u5b9a\u6027<\/td>\n\u7535\u5b50\u5668\u4ef6<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u7eff\u8272\u5316\u5b66\u7684\u5148\u950b<\/h4>\n

\u5728\u5168\u7403\u5021\u5bfc\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u80cc\u666f\u4e0b\uff0c\u7eff\u8272\u5316\u5b66\u5df2\u6210\u4e3a\u5316\u5b66\u5de5\u4e1a\u7684\u91cd\u8981\u53d1\u5c55\u65b9\u5411\u3002TMEDA\u5728\u8fd9\u65b9\u9762\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u6f5c\u529b\u3002\u901a\u8fc7\u4f18\u5316\u5408\u6210\u5de5\u827a\uff0c\u51cf\u5c11\u526f\u4ea7\u7269\u548c\u5e9f\u5f03\u7269\u7684\u4ea7\u751f\uff0cTMEDA\u53ef\u4ee5\u5e2e\u52a9\u5b9e\u73b0\u66f4\u52a0\u73af\u4fdd\u7684\u751f\u4ea7\u8fc7\u7a0b\u3002\u4f8b\u5982\uff0c\u91c7\u7528\u751f\u7269\u50ac\u5316\u6280\u672f\u66ff\u4ee3\u4f20\u7edf\u7684\u5316\u5b66\u8bd5\u5242\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u964d\u4f4e\u80fd\u8017\uff0c\u8fd8\u80fd\u663e\u8457\u51cf\u5c11\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002<\/p>\n

\u751f\u7269\u533b\u5b66\u9886\u57df\u7684\u521b\u65b0<\/h4>\n

\u5728\u751f\u7269\u533b\u5b66\u9886\u57df\uff0cTMEDA\u7684\u5e94\u7528\u4e5f\u5728\u9010\u6e10\u589e\u591a\u3002\u5b83\u88ab\u7528\u4e8e\u836f\u7269\u8f93\u9001\u7cfb\u7edf\u7684\u5f00\u53d1\uff0c\u5e2e\u52a9\u836f\u7269\u66f4\u7cbe\u51c6\u5730\u5230\u8fbe\u75c5\u7076\u90e8\u4f4d\uff0c\u63d0\u9ad8\u6cbb\u7597\u6548\u679c\u7684\u540c\u65f6\u51cf\u5c11\u526f\u4f5c\u7528\u3002\u6b64\u5916\uff0cTMEDA\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u57fa\u56e0\u7f16\u8f91\u5de5\u5177\u7684\u4e00\u90e8\u5206\uff0c\u534f\u52a9\u79d1\u5b66\u5bb6\u4eec\u5f00\u5c55\u66f4\u6df1\u5165\u7684\u9057\u4f20\u5b66\u7814\u7a76\uff0c\u4e3a\u75be\u75c5\u7684\u65e9\u671f\u8bca\u65ad\u548c\u4e2a\u6027\u5316\u6cbb\u7597\u63d0\u4f9b\u65b0\u7684\u53ef\u80fd\u6027\u3002<\/p>\n

\u7ed3\u8bed<\/h4>\n

\u5c55\u671b\u672a\u6765\uff0c\u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5c06\u7ee7\u7eed\u4ee5\u5176\u72ec\u7279\u7684\u6027\u8d28\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u63a8\u52a8\u79d1\u6280\u8fdb\u6b65\u548c\u793e\u4f1a\u53d1\u5c55\u3002\u65e0\u8bba\u662f\u65b0\u6750\u6599\u7684\u63a2\u7d22\uff0c\u8fd8\u662f\u7eff\u8272\u5316\u5b66\u7684\u5b9e\u8df5\uff0cTMEDA\u90fd\u5c06\u4ee5\u5176\u4e0d\u53ef\u66ff\u4ee3\u7684\u5730\u4f4d\uff0c\u5f15\u9886\u6211\u4eec\u8d70\u5411\u66f4\u52a0\u7f8e\u597d\u7684\u660e\u5929\u3002\u8ba9\u6211\u4eec\u5171\u540c\u671f\u5f85\u8fd9\u4e2a\u5316\u5b66\u7470\u5b9d\u5728\u672a\u6765\u7efd\u653e\u51fa\u66f4\u52a0\u8000\u773c\u7684\u5149\u8292\u3002<\/p>\n

\u6269\u5c55\u9605\u8bfb:https:\/\/www.cyclohexylamine.net\/catalyst-tmr-3-tmr-3-catalyst-dabco-tmr\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/40380<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/-T120-1185-81-5-didodecylthio-dibutyltin.pdf<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/tegoamin-as-1-catalyst-cas68439-24-2-degussa-ag\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/143<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/44625<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/high-quality-cas-136-53-8-zinc-octoate-ethylhexanoic-acid-zinc-salt\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/lupragen-n500-catalyst-basf\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/39796<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/169<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

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